Quizalofop-p-ethyl

Quizalofop-p-ethyl Basic information
Product Name:Quizalofop-p-ethyl
Synonyms:QUIZALOFOP-PETHYLESTER;2-(4-((6-chloro-2-quinoxalinyl)oxy)phenoxy)-, ethyl ester, (r)-propanoic acid;DPX-Y6202;Ethyl (2R)-2-[4-[(6-chloro-2-quinoxalinyl)oxy]phenoxy]propionate;EXP-3864;FBC-32197;Quizalofop ethyl ester;DPX-Y6202, Quinofop-ethyl, Ethyl (R)-2-[4-(6-chloro-2-quinoxalyloxy)phenoxy]propionate
CAS:100646-51-3
MF:C19H17ClN2O4
MW:372.8
EINECS:
Product Categories:API;Aromatics;INSECTICIDE;Chiral Reagents;Heterocycles
Mol File:100646-51-3.mol
Quizalofop-p-ethyl Structure
Quizalofop-p-ethyl Chemical Properties
Melting point 76-77°C
Boiling point 220 °C
density 1.301±0.06 g/cm3(Predicted)
Fp >100 °C
storage temp. Store at 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form neat
pka-1.39±0.48(Predicted)
Water Solubility 0.04 g/100 mL
CAS DataBase Reference100646-51-3(CAS DataBase Reference)
EPA Substance Registry SystemQuizalofop-P-ethyl (100646-51-3)
Safety Information
Hazard Codes Xn
Risk Statements 21/22
Safety Statements 36/37
RIDADR UN3077 9/PG 3
WGK Germany 3
RTECS UA2458257
HS Code 29333990
MSDS Information
Quizalofop-p-ethyl Usage And Synthesis
UsesPost-emergence herbicide for control of grassy weeds in broad-leaved crops. Herbicide.
DefinitionChEBI: Quizalofop-P-ethyl is an ethyl 2-{4-[(6-chloroquinoxalin-2-yl)oxy]phenoxy}propanoate that has R configuration. A proherbicide for quizalofop-P, it is used to control annual and perennial grass weeds in a variety of crops, including potatoes, sugar beet, peanuts, cotton and flax. It has a role as a proherbicide and an agrochemical. It is an ethyl 2-{4-[(6-chloroquinoxalin-2-yl)oxy]phenoxy}propanoate and a quinoxaline herbicide. It is functionally related to a quizalofop-P. It is an enantiomer of a (S)-quizalofop-ethyl.
Purification MethodsThis (±)-herbicide forms white crystals from Me2CO/EtOH and sublimes in vacuo. Large quantities can be distilled at high vacuum. Its solubilities at 20o in g/10mL are 0.09 (EtOH), 1.1 (Me2CO), 1.2 (xylene), 2.9 (*C6H6), and is nearly insoluble in H2O (0.3mg/L). The (±)-acid has [95977-28-9]. The R-ester enantiomer has m 76-77o (pale brown crystals from EtOH), [ ] D 20 + 3 5 . 9o (EtOH). It is the more active fatty acid synthase inhibitor (designated DPX-Y6202) used to control grassy weeds in broadleaf crops.
Trinexapac-ethyl Ethyl 2-bromopropionate Quizalofop-ethyl PROPAQUIZAFOP phenoxybenzamine Ethyl formate Ethylparaben Ethoxyquin Calcium Propionate ISOXADIFEN-ETHYL 2-Ethoxyethanol Diethyl ether chloroquinoline Ethyl acetate Quizalofop-p-tefuryl Quizalofop-p-ethyl Dimethyl succinate QUIZALOFOP-ETHYL D3 (3,3,3-D3)

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