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Bis-(triphenylphosphino)-cuprous borohydride

Bis-(triphenylphosphino)-cuprous borohydride Basic information
Product Name:Bis-(triphenylphosphino)-cuprous borohydride
Synonyms:Bis(triphenylphosphine)copper Tetrahydroborate, (PPh3)2CuBH4;BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYD;Copper,[tetrahydroborato(1-)-kH,kH']bis(triphenylphosphine)-,(T-4)-;BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYDRIDE;BIS(TRIPHENYLPHOSPHINE)COPPER(I) TETRAHYDRIDOBORATE;BIS(TRIPHENYLPHOSPHINE)COPPER TETRAHYDROBORATE;bis-(triphenylphosphino)-cuprous borohydride;Copper bis(trimethylphosphine)(tetrahydroborate)
CAS:16903-61-0
MF:2C18H15P.Cu.BH4
MW:602.97
EINECS:240-951-0
Product Categories:Cu;B (Classes of Boron Compounds);Classes of Metal Compounds;Cu (Copper) Compounds;Reduction;Synthetic Organic Chemistry;Tetrahydroborates;Transition Metal Compounds
Mol File:16903-61-0.mol
Bis-(triphenylphosphino)-cuprous borohydride Structure
Bis-(triphenylphosphino)-cuprous borohydride Chemical Properties
Melting point 164 °C (dec.)(lit.)
storage temp. Store below +30°C.
form powder to crystal
color White to Almost white
Sensitive Moisture Sensitive
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
CAS DataBase Reference16903-61-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-15
Safety Statements 26-60-43-37-7/8
RIDADR 2813
WGK Germany 3
F 9-21
HazardClass 4.3
PackingGroup III
HS Code 29319019
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Bis-(triphenylphosphino)-cuprous borohydride Usage And Synthesis
UsesBis(triphenylphosphine)copper tetrahydroborate (CAS# 16903-61-0) is an organometallic catalyst used in the enantioseletive radical oxytrifluoromethylation of alkenes with alcohols. Bis(triphenylphosphine)copper tetrahydroborate is also used in the preparation of tungsten, ruthenium and copper cluster complexes.
Bis-(triphenylphosphino)-cuprous borohydride Preparation Products And Raw materials
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Bis(triphenylphosphine)nickel(II)chloride Copper(I) Cyanide Trimethylphosphine Copper Sodium triacetoxyborohydride COPPER PHOSPHORUS Sodium borohydride METHYLPHOSPHINE BORANE COMPLEX BORANE-DIPHENYLPHOSPHINE COMPLEX BORANE-TRIPHENYLPHOSPHINE COMPLEX Potassium borohydride Bis-(triphenylphosphino)-cuprous borohydride GOLD COAST SOLUTION NO 1 Sodium cyanoborohydride Lithium borohydride Triphenylphosphine Copper oxychloride
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