ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organomagnesium 4-Methoxyphenylmagnesium bromide

4-Methoxyphenylmagnesium bromide

4-Methoxyphenylmagnesium bromide Basic information
Product Name:4-Methoxyphenylmagnesium bromide
Synonyms:4-Methoxyphenylmagnesium Bromide 1.0 M In Tetrahydrofuran;4-METHOXYPHENYLMAGNESIUM BROMIDE 0.5 M IN THF;4-Methoxyphenylmagnesium bromide, 1M solution in THF;4-anisylmagnesium bromide, 0.5m in thf;4-Methoxyphenylmagnesium bromide1M solution in THFAcroSeal§3;(4-Methoxyphenyl)bromomagnesium;4-Methoxyphenylbromomagnesium;p-Anisylbromomagnesium
CAS:13139-86-1
MF:C7H7BrMgO
MW:211.34
EINECS:
Product Categories:Chemical Synthesis;Grignard Reagents;Aryl;Grignard Reagents;Organometallic Reagents;Organometallic Reagents
Mol File:13139-86-1.mol
4-Methoxyphenylmagnesium bromide Structure
4-Methoxyphenylmagnesium bromide Chemical Properties
Boiling point 65-67 °C
density 0.955 g/mL at 25 °C
Fp −4 °F
storage temp. Flammables + water-Freezer (-20°C)e area
form Liquid
color Yellow to brown
Water Solubility Severe reaction
Sensitive Air & Moisture Sensitive
Exposure limitsACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
Safety Information
Hazard Codes F,C
Risk Statements 11-14-19-22-34-14/15-40-37
Safety Statements 16-26-33-36/37/39-45-6A-43B
RIDADR UN 2924 3/PG 2
WGK Germany -
HazardClass 4.3
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
4-Methoxyphenylmagnesium bromide Usage And Synthesis
Chemical PropertiesClear to brown solution when properly stored
Uses4-Methoxyphenylmagnesium bromide is applied in Grignard-reactions as a reagent for the introduction of the 4-methoxyphenyl group.
4-Methoxyphenylmagnesium bromide Preparation Products And Raw materials
Preparation Products(4-METHOXYPHENYL)DIPHENYLSULFONIUM TRIFLATE-->4-METHOXYPHENETHYL BROMIDE-->4,4'-DIMETHOXYBENZHYDROL-->4-Methoxybiphenyl-->4'-METHOXY-2,2,2-TRIFLUOROACETOPHENONE-->4-METHOXYAZOBENZENE-->Bis(4-methoxyphenyl)phosphine oxide-->4-Methoxytriphenylchloromethane
PHENYLMAGNESIUM BROMIDE Magnesium bromide hexahydrate Rocuronium bromide 3,4-DIMETHOXYPHENYLMAGNESIUM BROMIDE Vecuronium bromide Methylmagnesium Bromide Dimidium bromide Anisole (Trifluoromethoxy)benzene Sodium bromate 4-PHENOXYPHENYLMAGNESIUM BROMIDE Vinylmagnesium bromide 3-FLUORO-4-METHOXYPHENYLMAGNESIUM BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN,3-FLUORO-4-METHOXYPHENYLMAGNESIUM BROMIDE p-Anisidine Ethidium bromide Allyl bromide 4-Methoxyphenylmagnesium bromide Methyl bromide
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