ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Hydrocarbon halides 3-Chlorobenzyl bromide

3-Chlorobenzyl bromide

3-Chlorobenzyl bromide Basic information
Product Name:3-Chlorobenzyl bromide
Synonyms:à-bromo-3-chlorotoluene;3-Chlorobenzyl bromide 97%;A-BROMO-3-CHLOROTOLUENE;3-Chlorobenzyl bromide, 98+%;Benzene, 1-(bromomethyl)-3-chloro-;m-Chloro-α-bromotoluene;α-Bromo-m-chlorotoluene;3-Chlorobenzyl bromi
CAS:766-80-3
MF:C7H6BrCl
MW:205.48
EINECS:212-171-0
Product Categories:Benzyl
Mol File:766-80-3.mol
3-Chlorobenzyl bromide Structure
3-Chlorobenzyl bromide Chemical Properties
Melting point 15 °C
Boiling point 109-110 °C/12 mmHg (lit.)
density 1.565 g/mL at 25 °C (lit.)
refractive index n20/D 1.588(lit.)
Fp >230 °F
storage temp. Inert atmosphere,2-8°C
form powder to lump to clear liquid
Specific Gravity1.565
color White or Colorless to Yellow
Water Solubility DECOMPOSES
Sensitive Lachrymatory
BRN 636504
CAS DataBase Reference766-80-3(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-(bromomethyl)-3-chloro-(766-80-3)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3265 8/PG 2
WGK Germany 3
F 19
Hazard Note Corrosive/Lachrymatory
HazardClass 6.1
PackingGroup III
HS Code 29039990
MSDS Information
ProviderLanguage
1-(Bromomethyl)-3-chlorobenzene English
SigmaAldrich English
ACROS English
ALFA English
3-Chlorobenzyl bromide Usage And Synthesis
Chemical PropertiesColorless liquid
Uses3-Chlorobenzyl bromide was used in the synthesis of symmetrical and unsymmetrical benzyl thioethers. It was used as starting reagent during the synthesis of 1-(3-chlorobenzyl)-2-(pyrrolidin-1-ylmethyl)-1H-benzimidazole dihydrochloride.
General Description3-Chlorobenzyl bromide reacts with aminoethanol and NaH to yield aminoethyl 3-chlorobenzyl ether.
3-Chlorobenzyl bromide Preparation Products And Raw materials
Preparation Products(3-CHLORO-PHENYL)-METHANESULFONYL CHLORIDE-->L-3-Chlorophenylalanine-->Butylamine Hydrobromide-->3-CHLORO-N-METHYLBENZYLAMINE-->CytochroMe P450 14a-deMethylase inhibitor 1f-->3-[(3-CHLOROBENZYL)OXY]BENZALDEHYDE-->1-(3-CHLOROBENZYL)-2-OXO-1,2-DIHYDRO-3-PYRIDINECARBOXYLIC ACID-->2-(3-CHLOROBENZYLOXY)BENZALDEHYDE-->1-[(3-chlorophenyl)methyl]-1H-pyrazol-4-amine-->3-chloro-4-[(3-chlorophenyl)methoxy]benzoic acid
4-AZIDO-3-CHLOROBENZYL BROMIDE,4-AZIDO-3-CHLOROBENZYL BROMIDE 3-Bromo-5-chlorobenzyl bromide,3-Bromo-5-chlorobenzyl bromide 2,3-DIBROMO-3-(3,4-DICHLOROPHENYL)-1-(2-NITROPHENYL)PROPAN-1-ONE 1-[2-(BENZYLOXY)PHENYL]-2,3-DIBROMO-3-(3,4-DICHLOROPHENYL)PROPAN-1-ONE 3-FLUORO-4-CHLOROBENZYL BROMIDE,3-FLUORO-4-CHLOROBENZYL BROMIDE 3-CHLORO-4-(TRIFLUOROMETHOXY)BENZYL BROMIDE 3-CHLORO-2-FLUORO-5-(TRIFLUOROMETHYL)BENZYL BROMIDE 1,4-BIS(BROMMETHYL)-2,5-DICHLOROBENZENE alpha-Bromo-2-chlorophenylacetic acid BRETYLIUM TOSYLATE Clidinium bromide 3-CHLORO-2-FLUORO-6-(TRIFLUOROMETHYL)BENZYL BROMIDE 2-BROMO-6-CHLOROBENZYL BROMIDE,2-BROMO-6-CHLOROBENZYL BROMIDE BCDMH 1,2-Dichloro-4-(chloromethyl)benzene Chlorobromoisocyanurate 2-Fluoro-5-chlorobenzyl bromide,2-Fluoro-5-chlorobenzyl bromide 3-CHLOROBENZAL BROMIDE
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