1,2-PHENYLENE PHOSPHOROCHLORIDATE

1,2-PHENYLENE PHOSPHOROCHLORIDATE Basic information
Product Name:1,2-PHENYLENE PHOSPHOROCHLORIDATE
Synonyms:3,2-benzodioxaphosphole,2-chloro-2-oxide;o-Phenylenephosphorochloridate;2-CHLORO-1,3,2-BENZODIOXAPHOSPHOLE 2-OXIDE;1,2-PHENYLENE PHOSPHOROCHLORIDATE, TECH.;1,2-PHENYLENE PHOSPHOROCHLORIDATE;1,2-PHENYLENE CHLOROPHOSPHATE;2-Chloro-1,3,2-benzodioxaphosphole 2-oxide, o-Phenylene chlorophosphate;o-Phenylene chlorophosphate
CAS:1499-17-8
MF:C6H4ClO3P
MW:190.52
EINECS:216-106-7
Product Categories:
Mol File:1499-17-8.mol
1,2-PHENYLENE PHOSPHOROCHLORIDATE Structure
1,2-PHENYLENE PHOSPHOROCHLORIDATE Chemical Properties
Melting point 56-62 °C
Boiling point 120 °C9 mm Hg(lit.)
density 1.57±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,Store in freezer, under -20°C
BRN 142368
EPA Substance Registry System1,3,2-Benzodioxaphosphole, 2-chloro-, 2-oxide (1499-17-8)
Safety Information
Hazard Codes C
Risk Statements 14-34
Safety Statements 26-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
10
HazardClass 8
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
1,2-PHENYLENE PHOSPHOROCHLORIDATE Usage And Synthesis
UsesReactant for preparation of:
  • Uridine diphosphate-glucose derivatives as potential chain terminators of β-glucan biosynthesis with antifungal activity
  • Vinyloxy phosphorus monomers

  • Phosphorylation agent
Purification MethodsAfter distilling it in a vacuum, it sets to a colourless solid. It is soluble in pet ether, *benzene and slightly soluble in Et2O. [Khwaja et al. J Chem Soc (C) 2092 1970, Anschütz & Broeker Justus Liebigs Ann Chem 454 109 1927, Beilstein 6 IV 5602.]
1,2-PHENYLENE PHOSPHOROCHLORIDATE Preparation Products And Raw materials
DIMETHYLCHLOROPHOSPHITE DIMETHYL PHOSPHOROCHLORIDATE 1,2-PHENYLENE PHOSPHOROCHLORIDITE 1,2-PHENYLENE PHOSPHOROCHLORIDATE Dimethyl phosphite

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