Benalaxyl

Benalaxyl Basic information
Product Name:Benalaxyl
Synonyms:METHYL2-(N-PHENYLACETYL-N-(2,6-DIMETHYLPHENYL)AMINO)PROPANOATE;N-(2,6-dimethylphenyl)-N-(phenylacetyl)-DL-alanine;methyl-N-phenylacetyl-N-2,6-dimethyl phenyl-DL-alaninate;TF 3675;benalaxyl methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)-DL-alaninate;Benalaxyi;Benalaxyl 250mg [71626-11-4];(±)-N-(2,6-Dimethylphenyl)-N-(phenylacetyl)alanine methyl ester
CAS:71626-11-4
MF:C20H23NO3
MW:325.4
EINECS:275-728-7
Product Categories:A-BPesticides;Alpha sort;Amide structureAlphabetic;B;BA - BH;Fungicides;FUNGICIDE;Pesticides&Metabolites;Aromatics;Intermediates & Fine Chemicals;Pharmaceuticals
Mol File:71626-11-4.mol
Benalaxyl Structure
Benalaxyl Chemical Properties
Melting point 78-80°C
Boiling point 463.59°C (rough estimate)
density 1.2700
vapor pressure 6.6 x 10-5 Pa (25 °C)
refractive index 1.5614 (estimate)
storage temp. 0-6°C
solubility Chloroform (Slightly), Methanol (Slightly)
Water Solubility 28.6 mg l-1 (20 °C)
form neat
pka1.52±0.50(Predicted)
Merck 13,1028
BRN 3001587
NIST Chemistry ReferenceBenalaxyl(71626-11-4)
EPA Substance Registry SystemBenalaxyl (71626-11-4)
Safety Information
Hazard Codes N
Risk Statements 50/53
Safety Statements 60-61
RIDADR UN 3077
WGK Germany 2
RTECS AY5993200
HS Code 29242990
ToxicityLD50 in rats (mg/kg): 4200 orally; 1100 i.p.; LC50 (96 hr) in rainbow trout: 3.75 mg/l (Bergamaschi)
MSDS Information
Benalaxyl Usage And Synthesis
UsesAn acylamino acid fungicide.
UsesAgricultural fungicide.
UsesBenalaxyl is used for the control of Oomycetes on a wide range of crops, fruit, flowers, ornamentals and turf.
DefinitionChEBI: Methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)alaninate is an alanine derivative that is the N-phenylacetyl derivative of methyl N-(2,6-dimethylphenyl)alaninate It is an alanine derivative, an aromatic amide, a carboxamide and a methyl ester.
Metabolic pathwayThe fate of 14C-benalaxyl as affected by mancozeb is determined on the surface and in the tissues of grape leaves 7 days after the single foliar application of a mixture with mancozeb. The main oxidative scheme with rat liver microsomes is quite similar to that observed in plants. The only differences are represented by a further hydroxylation on the second ortho methyl group, and only traces of the meta hydroxylation take place on the xylene ring.
DegradationBenalaxyl is stable in aqueous media over a wide pH range but it is hydrolysed in concentrated alkali. Its DT50 at pH 9 and 25 °C is 86 days (PM). It is reasonably stable to sunlight in aqueous solution. When irradiated in solution with UV light (254 nm) it is degraded with a half-life of 55 minutes (Pirisi et al., 1996). Products were compounds 2 and 3 (see Scheme 1) which are common also to metalaxyl and furalaxyl. These were detected in a non-labelled study. Under simulated sunlight its half-life was 167 days.
Benalaxyl Preparation Products And Raw materials
Raw materialsNickel-->Cyclohexane-->2,6-Dimethylaniline-->Methyl propionate-->Methyl acetate-->Phenylacetyl chloride-->methyl N-(2,6-dimethylphenyl)-DL-alaninate
Preparation ProductsBenalaxyl-M
Methylparaben Chlorodimethylphenylsilane β-Alanine Methyl N-ACETYL-L-TYROSINE ETHYL ESTER Acetylacetone Benomyl tributyl acetocitrate L-Alanine Metalaxyl Tribenuron methyl Oxadixyl Methanol Methyl propionate Methyl salicylate Methyl acrylate DL-Alanine N,N-Dimethyl-1,4-phenylenediamine

Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.