2-AMINO-4-CHLOROTHIOPHENOL

2-AMINO-4-CHLOROTHIOPHENOL Basic information
Product Name:2-AMINO-4-CHLOROTHIOPHENOL
Synonyms:2-AMINO-4-CHLOROTHIOPHENOL;BUTTPARK 35\10-17;4-Chloro-2-Aminothio-Phenol;2-amino-4-chloro thoiphenol;4-Chloro-2-aminobenzenethiol;5-Chloro-2-mercaptoaniline, 2-Amino-4-chlorobenzenethiol, 2-Amino-4-chlorophenyl mercaptan;2-Amino-4-chlorobenzenethiol 96%;2-AMINO-4-CHLORO THIOPHENOL 97.0%MIN
CAS:1004-00-8
MF:C6H6ClNS
MW:159.64
EINECS:
Product Categories:Sulphur Derivatives;Phenol&Thiophenol&Mercaptan;Phenoles and thiophenoles;Organic Building Blocks;Sulfur Compounds;Thiols/Mercaptans
Mol File:1004-00-8.mol
2-AMINO-4-CHLOROTHIOPHENOL Structure
2-AMINO-4-CHLOROTHIOPHENOL Chemical Properties
Melting point 56-61 °C (lit.)
Boiling point 100 °C(Press: 1 Torr)
density 1.372±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
Water Solubility Practically insoluble in water
solubility Chloroform (Slightly), Methanol (Sparingly)
form powder to crystaline
pka7.35±0.11(Predicted)
color White to Light yellow to Green
Sensitive Stench
Stability:Air sensitive, Light sensitive
CAS DataBase Reference1004-00-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR UN 3261 8/PG 3
WGK Germany 3
Hazard Note Irritant/Stench
HazardClass 8
PackingGroup III
HS Code 29309090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
2-AMINO-4-CHLOROTHIOPHENOL Usage And Synthesis
Chemical PropertiesYellow crystalline
Uses2-Amino-4-chlorobenzenethiol may be used in the synthesis of:
  • 2,3-dihydro-1,5-benzothiazepin-4-(5H)-ones
  • 8-chloro-1-azaphenothiazine
  • 5-chloro-2-(4-methoxyphenyl)-2,3-dihydro-1,3,2-benzothiazaphosphole 2-sulfide
General Description2-Amino-4-chlorobenzenethiol reacts with aromatic aldehydes and cyclohexanecarboxaldehyde to afford the corresponding thiazole and thiazoline derivatives. It undergoes oxidation in the presence of 1-n-butyl-3-methylimidazolium methylselenite, [bmim][SeO2(OCH3)] to form the corresponding symmetrical disulfide.
2-AMINO-4-CHLOROTHIOPHENOL Preparation Products And Raw materials
Preparation Products5-Chloro-2-mercaptobenzothiazole-->2-Chlorophenothiazine-->5-CHLORO-2-BENZOTHIAZOLECARBOXYLIC ACID ETHYL ESTER-->5-CHLORO-2-(4-METHOXYPHENYL)BENZO[D]THIAZOLE
5-chloro-2-[(4-chlorophenyl)sulfanyl]aniline BIS(2-AMINO-4-CHLOROPHENYL)DISULPHIDE 5-CHLORO-2-BENZOTHIAZOLINONE 4-AMINO-6-CHLORO-BENZENE-1,3-DISULFONYL DICHLORIDE 2-Chlorophenothiazine 2,2'-DINITRO-4,4'-DICHLORO DIPHENYL DISUFIDE 4-CHLORO-2-NITRO-1-(PHENYLTHIO)BENZENE 3,4-Dichloroaniline-6-sulfonic acid 2-Amino-4-chlorothiophenol hydrochloride Trichlormethiazide 4-CHLORO-2-NITRO-1-(PHENYLSULFONYL)BENZENE IR-140 2-AMINO-5-CHLOROTHIOPHENOL 2-AMINO-3-CHLOROTHIOPHENOL Chlorothiazide 2-Amino-4-chloro-5-methylbenzenesulfonic acid 2-Aminobenzenethiol 4-Amino-6-chlorobenzene-1,3-disulfonamide

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