2-(Trifluoromethyl)benzaldehyde

2-(Trifluoromethyl)benzaldehyde Basic information
Product Name:2-(Trifluoromethyl)benzaldehyde
Synonyms:o-Tolualdehyde, alpha,alpha,alpha-trifluoro-;O-(TRIFLUOROMETHYL)BENZALDEHYDE;OTF-BAD;ORTHO-TRIFLUOROMETHYL-BENZALDEHYDE;AKOS BBS-00003172;ALPHA,ALPHA,ALPHA-TRIFLUORO-O-TOLUALDEHYDE;A,A,A-TRIFLUORO-O-TOLUALDEHYDE;à,à,à-trifluoro-o-tolualdehyde
CAS:447-61-0
MF:C8H5F3O
MW:174.12
EINECS:207-185-9
Product Categories:Benzotrifluoride Series;Benzaldehyde;Aromatic Aldehydes & Derivatives (substituted);Benzene series;Miscellaneous
Mol File:447-61-0.mol
2-(Trifluoromethyl)benzaldehyde Structure
2-(Trifluoromethyl)benzaldehyde Chemical Properties
Melting point -40 °C
Boiling point 70-71 °C (16 mmHg)
density 1.32 g/mL at 25 °C(lit.)
refractive index n20/D 1.466(lit.)
Fp 142 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Soluble in most organic solvents.
form Liquid
Specific Gravity1.320
color Clear colorless to slightly yellow
Sensitive Air Sensitive
BRN 2045512
LogP2.67
CAS DataBase Reference447-61-0(CAS DataBase Reference)
NIST Chemistry ReferenceBenzaldehyde, 2-(trifluoromethyl)-(447-61-0)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39-37/39-36
RIDADR UN 1993 3/PG III
WGK Germany 3
HazardClass IRRITANT
PackingGroup III
HS Code 29124990
MSDS Information
ProviderLanguage
alpha,alpha,alpha-Trifluoro-o-tolualdehyde English
SigmaAldrich English
ACROS English
ALFA English
2-(Trifluoromethyl)benzaldehyde Usage And Synthesis
Chemical Propertiesclear colorless to slightly yellow liquid
Uses2-(Trifluoromethyl)benzaldehyde has been used in the preparation of ω-(dimethylamino)-alkylethyl-4(-2-(trifluorormethyl)phenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylates, methyl (E)-2-[2-[(E)-2-(2-trifluoromethylphenyl)vinyl]-phenyl]-3-methoxyacrylate via Wittig-Horner reaction. It is a reagent used as electrophilic component in a wide array of reactions.
Synthesis Reference(s)Tetrahedron, 49, p. 2151, 1993 DOI: 10.1016/S0040-4020(01)80359-8
2-(Trifluoromethyl)benzoic acid 2-(Trifluoromethyl)benzoyl chloride 2-Methylbenzotrifluoride 4-(Trifluoromethoxy)benzaldehyde (Trifluoromethyl)trimethylsilane 3-(Trifluoromethyl)benzaldehyde p-Tolualdehyde sodium benzaldehyde-o-sulfonate 3-(trifluoromethyl) Cinnamaldehyde Trifluoromethanesulfonic anhydride Trifluoromethyl Salicylaldehyde 4-(Trifluoromethyl)benzaldehyde, 97+%,4-(Trifluoromethyl)benzaldehyde , (p-Trifluoromethylbenzaldehyde) Benzaldehyde m-Tolualdehyde 3,4-Dimethylbenzaldehyde 2-Nitrobenzaldehyde Diethylstilbestrol

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