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| | Benzaldoxime Basic information |
| Product Name: | Benzaldoxime | | Synonyms: | ANTI-BENZALDOXIME;BENZALDOXIME;AKOS 91587;ALPHA-BENZALDOXIME;BENZALDEHYDE OXIME 98%;benzaldehyde oxime, predominantly (e)-isomer;anti-benzaldehyde oxime;a-Benzyl monoxime | | CAS: | 932-90-1 | | MF: | C7H7NO | | MW: | 121.14 | | EINECS: | 213-261-2 | | Product Categories: | Aromatics Compounds;Aromatics | | Mol File: | 932-90-1.mol |  |
| | Benzaldoxime Chemical Properties |
| Melting point | 30-33 °C | | Boiling point | 118-120°C 10mm | | density | 1,11 g/cm3 | | refractive index | 1.59-1.592 | | Fp | 108°C | | storage temp. | Store below +30°C. | | solubility | methanol: 0.1 g/mL, clear | | form | low melting solid | | pka | 10.80±0.70(Predicted) | | color | Colourless to light yellow | | Water Solubility | Slightly soluble in water. Soluble in ethanol and ether. | | BRN | 774138 | | CAS DataBase Reference | 932-90-1(CAS DataBase Reference) | | NIST Chemistry Reference | Benzaldehyde, oxime(932-90-1) | | EPA Substance Registry System | Benzaldehyde, oxime (932-90-1) |
| | Benzaldoxime Usage And Synthesis |
| Chemical Properties | White Solid | | Uses | Benzaldoxime is an intermediate used to prepare Δ2-Isoxazoline derivatives as DNA methyltransferase 1 inhibitors. It is also used in the synthesis of potent 1,2,4-Oxadiazole EthR inhibitors. | | Uses | Oximes are used as a peel-preventing additive in paints and lacquers. It acts as an antioxidant against oxidative drying materials which forms sticky skin with air oxygen. Oximes are used as chemical building block for the synthesis of agrochemicals and pharmaceuticals. In medicine application, Oxime structure is effective in cholinesterase reactivators to treat the poisoning by organophosphates. Oxime is used as a ligand in transition-metal complex catalyst chemistry. Oxime acts as an antioxidant, radical scavenger which find applications in textile, plastic, paint, detergent, and rubber industry. | | Synthesis Reference(s) | Tetrahedron, 51, p. 11305, 1995 DOI: 10.1016/0040-4020(95)00692-2
Tetrahedron Letters, 36, p. 1903, 1995 DOI: 10.1016/0040-4039(95)00108-O | | Purification Methods | Crystallise the oxime from diethyl ether by adding pet ether (b 60-80o). The syn-isomer [622-32-2] has b 121-124o/12mm, m 34-36o. [Beilstein 7 H 218, 7 IV 527.] |
| | Benzaldoxime Preparation Products And Raw materials |
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