ChemicalBook Product Catalog Chemical Reagents Organic reagents Silane PHENYLTHIOTRIMETHYLSILANE

PHENYLTHIOTRIMETHYLSILANE

PHENYLTHIOTRIMETHYLSILANE Basic information
Product Name:PHENYLTHIOTRIMETHYLSILANE
Synonyms:S-(TRIMETHYLSILYL)BENZENETHIOL;S-(TRIMETHYLSILYL)THIOPHENOL;PHENYLTHIOTRIMETHYLSILANE;PHENYL TRIMETHYLSILYL SULFIDE;TRIMETHYL(PHENYLTHIO)SILANE;Phenylthiotrimethylsilane(S-Trimethylsilylthiophenol);(Phenylthio)trimethylsilane, Phenyl trimethylsilyl sulfide, S-(Trimethylsilyl)thiophenol;Trimethylsilylthiobenzene
CAS:4551-15-9
MF:C9H14SSi
MW:182.36
EINECS:224-916-7
Product Categories:Monoalkoxysilanes;Protection & Derivatization Reagents (for Synthesis);Si (Classes of Silicon Compounds);Si-O Compounds;Synthetic Organic Chemistry
Mol File:4551-15-9.mol
PHENYLTHIOTRIMETHYLSILANE Structure
PHENYLTHIOTRIMETHYLSILANE Chemical Properties
Boiling point 72 °C/8 mmHg (lit.)
density 0.963 g/mL at 25 °C (lit.)
refractive index n20/D 1.532(lit.)
Fp 87 °F
storage temp. Flammables area
solubility sol organic solvents; incompatible with strong acids and strong oxidizing agents.
form clear liquid
color Colorless to Light yellow
Specific Gravity0.963
Water Solubility Hydrolyzes in water.
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Sensitive Moisture Sensitive
BRN 1905944
CAS DataBase Reference4551-15-9(CAS DataBase Reference)
EPA Substance Registry SystemSilane, trimethyl(phenylthio)- (4551-15-9)
Safety Information
Hazard Codes Xn
Risk Statements 10-20-38
Safety Statements 23-28
RIDADR UN 1993 3/PG 3
WGK Germany 3
F 3-10-13-21
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
PHENYLTHIOTRIMETHYLSILANE Usage And Synthesis
Chemical Propertiesclear colorless to light yellow liquid
Physical propertiesbp 93–99 °C/12 mmHg; d 0.967 g cm?3.
Uses(Phenylthio)trimethylsilane can be used in selective carbonyl protection; preparation of thioesters and cleavage of ethers.
Purification MethodsPhenylthio trimethylsilane (trimethyl phenylthio silane) [4551-15-9] M 182.4, b 95 -9 9o/12mm, d 4 0.97. Purification is as for phenyl trimethyl silylmethyl sulfide.
PHENYLTHIOTRIMETHYLSILANE Preparation Products And Raw materials
Preparation Products3-NITRO-4-(PHENYLSULFANYL)BENZENECARBALDEHYDE-->L-Cysteine, N-[(1,1-dimethylethoxy)carbonyl]-S-phenyl-, methyl ester
BIS(TRIMETHYLSILYL) SULFIDE (METHYLTHIO)TRIMETHYLSILANE (4-BROMOPHENYLTHIO)DIMETHYL-TERT-BUTYLSILANE 3-T-BDMSTHIOPHENYLBORONIC ACID PHENYLTHIOTRIMETHYLSILANE
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