4-Nitrophenylboronic acid pinacol ester

4-Nitrophenylboronic acid pinacol ester Basic information
Product Name:4-Nitrophenylboronic acid pinacol ester
Synonyms:4-NITROPHENYLBORONIC ACID PINACOL ESTER;4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)NITROBENZENE;4-Nitrobenzeneboronic acid, pinacol ester;4,4,5,5-tetramethyl-2-(4-nitrophenyl)-1,3,2-dioxaborolane;2-(4-Nitrophenyl)-4,4,5,5,-tetramethyl-1,3,2-dioxaborolane, 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene;1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(4-nitrophenyl)-;4-Nitrophenylboronic acid pinacol ester 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene;-Nitrophenylboronic acid pinacol ester
CAS:171364-83-3
MF:C12H16BNO4
MW:249.07
EINECS:
Product Categories:Aryl Boronate Esters;Boronate Esters;Aryl;Boronic Acids and Derivatives;Chemical Synthesis;Organometallic Reagents;blocks;BoronicAcids;NitroCompounds;Boronic ester;Organoborons;Pyrimidines
Mol File:171364-83-3.mol
4-Nitrophenylboronic acid pinacol ester Structure
4-Nitrophenylboronic acid pinacol ester Chemical Properties
Melting point 112-116 °C (lit.)
Boiling point 357.5±25.0 °C(Predicted)
density 1.14±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form powder or crystals
color White to Orange to Green
Water Solubility Slightly soluble in water.
CAS DataBase Reference171364-83-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 2
Hazard Note Harmful/Store Cold
HazardClass IRRITANT
HS Code 29333990
MSDS Information
ProviderLanguage
SigmaAldrich English
4-Nitrophenylboronic acid pinacol ester Usage And Synthesis
Chemical PropertiesWhite solid
UsesReactant involved in: • ;Synthesis of aryl azides 1• ;Arylation of allylic chlorides2• ;Syntehsis of RNA conjugates3• ;Alkoxycarbonylation4• ;Synthesis of mTOR and PI3K inhibitors as antitumor agents5• ;Electrooxidative synthesis of biaryls6
Usessuzuki reaction
Uses4-Nitrobenzeneboronic acid pinacol ester is a reactant involved in synthesis of aryl azides, arylation of allylic chlorides, synthesis of RNA conjugates, alkoxycarbonylation, synthesis of mTOR and PI3K inhibitors as antitumor agents, electro oxidative synthesis of biaryls.
Synthesis Reference(s)The Journal of Organic Chemistry, 60, p. 7508, 1995 DOI: 10.1021/jo00128a024
4-Aminophenylboronic acid (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Pinacol 2-Fluoro-4-nitrophenylboronic acid, pinacol ester 4-Nitrophenylboronic acid Tris(trimethylsilyl)phosphate 2,4,6-TRINITROBENZENESULFONIC ACID 2-METHYL-5-NITROPHENYLBORONIC ACID, PINACOL ESTER Sodium 3-nitrobenzenesulphonate p-Nitrobenzoic acid 4-Aminophenylboronic acid pinacol ester Nitrobenzene 4-Nitrobenzaldehyde 4-Nitrophenylboronic acid pinacol ester 4,4,5,5-TETRAMETHYL-2-(2-METHYL-4-NITROPHENYL)-1,3,2-DIOXABOROLANE Pinacolborane 1-Fluoro-2-nitrobenzene 1,3-Dinitrobenzene

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