ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organic zinc ZINC TRIFLUOROMETHANESULFONATE

ZINC TRIFLUOROMETHANESULFONATE

ZINC TRIFLUOROMETHANESULFONATE Basic information
Reaction
Product Name:ZINC TRIFLUOROMETHANESULFONATE
Synonyms:Zinc trifluoromethylsulfonate;Zn(OTf)2;Bis(trifluoromethanesulfonato)zinc;trifluoro-methanesulfonicacizincsalt;Trifluoromethane sulfonic acid zinc;Zinc trifluoromethanesulfonate, min. 98%;ZINC TRIFLUOROMETHANESULFONATE;ZINC TRIFLUOROMETHANESULPHONATE
CAS:54010-75-2
MF:C2F6O6S2Zn
MW:363.53
EINECS:258-922-6
Product Categories:metal triflate compounds;OTf&NTf series;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Other Metal;Metal Triflates;Synthetic Organic Chemistry;Transition Metal Compounds;Zn (Zinc) Compounds;triflate
Mol File:54010-75-2.mol
ZINC TRIFLUOROMETHANESULFONATE Structure
ZINC TRIFLUOROMETHANESULFONATE Chemical Properties
Melting point ≥300 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
form Powder
color White to light-gray
Water Solubility Soluble in water and acetonitrile. Slightly soluble in methanol. Insoluble in dichloromethane.
Sensitive Hygroscopic
BRN 4028195
Stability:hygroscopic
InChIInChI=1S/2CHF3O3S.Zn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2
InChIKeyCITILBVTAYEWKR-UHFFFAOYSA-L
SMILESC(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S([O-])(=O)=O.[Zn+2]
CAS DataBase Reference54010-75-2(CAS DataBase Reference)
EPA Substance Registry SystemMethanesulfonic acid, trifluoro-, zinc salt (54010-75-2)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
F 3-10
Hazard Note Irritant/Hygroscopic
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29049090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
ZINC TRIFLUOROMETHANESULFONATE Usage And Synthesis
Reaction
  1. Catalyst for the addition of acetylenes to carbonyls and nitrones.
  2. Claisen rearrangement.
  3. Catalyst for the enantioselective Henry and Aza-Henry reactions.
  4. Pd-catalyzed hydroalkylation of styrenes with zinc reagents.
Reactions of 54010-75-2
Chemical Propertieswhite to light-grey powder
UsesZinc trifluoromethanesulfonate acts as a catalyst for the preparation of dithioketals. It is used as a Lewis acid catalyst in silylation reactions. It is also used as a catalyst for greener amine synthesis by reductive amination with hydrogen gas.
General DescriptionWe are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Purification MethodsIt should be dried at 125o for 2hours at 3mm before use. It is soluble in CH2Cl2 but insoluble in pet ether. [Corey & Shimoji Tetrahedron Lett 24 169 1983.]
ZINC TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Raw materialsTrifluoromethanesulfonic acid-->Zinc carbonate
N-MethyltrifluoroMethanesulfonaMide Potassium trifluoromethanesulfonate PentaMethylene Bis[4-(10,15,20-triphenylporphyrin-5-yl)benzoate]dizinc(II) [Reagent for application of the exciton chirality Method] SILVER TRIFLUOROMETHANESULFONATE TRIFLUOROMETHANESULFONYL CHLORIDE Trifluoromethanesulfonic anhydride N-Phenyl-bis(trifluoromethanesulfonimide) Sodium trifluoromethanesulfonate Lithium bis(trifluoromethanesulphonyl)imide YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Trifluoromethanesulfonic acid Aluminum trifluoromethanesulfonate Lanthanum trifluoromethanesulfonate Lithium triflate TRIFLUOROMETHANESULFONIMIDE Trifluoromethane ZINC TRIFLUOROMETHANESULFONATE METHANE Zinc Triflate
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