2-Butyne

2-Butyne Basic information
Product Name:2-Butyne
Synonyms:2-Butyne,98%;But-2-yne;CH3CequivCCH3;Butyne;Crotonylenetylene;CROTONYLENE(DOT);2-BUTYNE 98%;Crotonylene, Dimethylacetylene
CAS:503-17-3
MF:C4H6
MW:54.09
EINECS:207-962-2
Product Categories:Acetylenic Hydrocarbons;Acetylenes;Alkynes;Building Blocks;Chemical Synthesis;Internal;Organic Building Blocks
Mol File:503-17-3.mol
2-Butyne Structure
2-Butyne Chemical Properties
Melting point -32 °C
Boiling point 27 °C(lit.)
density 0.691 g/mL at 25 °C(lit.)
vapor pressure 11.47 psi ( 20 °C)
refractive index n20/D 1.393(lit.)
Fp -25 °C
storage temp. 2-8°C
form Liquid
Specific Gravity0.691
color Clear colorless to light yellow
Water Solubility Not miscible in water.
BRN 1361340
CAS DataBase Reference503-17-3(CAS DataBase Reference)
EPA Substance Registry System2-Butyne (503-17-3)
Safety Information
Hazard Codes F+,Xi
Risk Statements 12-36/37/38
Safety Statements 16-26-36
RIDADR UN 1144 3/PG 1
WGK Germany 3
RTECS GQ7210000
TSCA Yes
HazardClass 3
PackingGroup I
HS Code 29012990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
2-Butyne Usage And Synthesis
Chemical Propertiesclear colorless to light yellow liquid
Uses2-Butyne is used to synthesize alkylated hydroquinones in the total synthesis of Vitamin E. It is also used as pharmaceutical intermediates.
General DescriptionA clear colorless liquid with a petroleum-like odor. Flash point below -4°F. Boiling point 81°F. Less dense than water and insoluble in water. Vapors heavier than air.
Air & Water ReactionsHighly flammable. Insoluble in water.
Reactivity Profile2-Butyne may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.
HazardFlammable, dangerous fire risk. Moderate explosion hazard.
Health HazardInhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Safety ProfileA simple asphyxiant. Very dangerous fire hazard when exposed to heat or flame; can react with oxidzing materials. Moderately explosive in the form of vapor when exposed to heat or flame. To fight fire, use foam, CO2, dry chemicals. See also ACETYLENE COMPOUNDS and ARGON (for a description of simple asphyxiants).
Purification MethodsStand it over sodium for 24hours, then fractionally distil it under reduced pressure into a cooled receiver. [Beilstein 1 IV 971.]
1-Phospha-1-butyne, 3,3-dimethyl- (3,3-Dimethyl-1-butyne)dicobalthexacarbonyl,98% 2,7-DIMETHYL-3,5-OCTADIYN-2,7-DIOL 3-HEXYN-1-OL 5-Oxa-2-octyne-1,7-diol Poly(oxy-1,2-ethanediyl), .alpha.,.alpha.-1,4-dimethyl-1,4-bis(3-methylbutyl)-2-butyne-1,4-diylbis.omega.-hydroxy- 4-(Dimethylphenylsilyl)-3-butyn-2-one 10-Propargyl-10-deazaaminopterin 4-(TERT-BUTYLDIMETHYLSILOXY)BUTYNE 1-Menthoxy-1-butyne OXOTREMORINE Ethyl 2-butynoate 1,1,3-Triphenylpropargyl alcohol 1-Butyne, 3-phenyl-1,3-bis(trimethylsilyl)- 3-Butyne-2-Ol98%,3-BUTYNE-2-OL 99% 1,1,1-TRIFLUORO-2-BUTYNE Phenylpropiolaldehyde 1,4-BIS(2-HYDROXYETHOXY)-2-BUTYNE, TECH. , 85%,Ethanol, 2,2-2-butyne-1,4-diylbis(oxy)bis-,2-BUTYNE-1,4-DIOLBIS(2-HYDROXYETHYL)ETHER(CA.50%ISOMER)

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