1,1,3,3-TETRAMETHYLDISILAZANE

1,1,3,3-TETRAMETHYLDISILAZANE Basic information
Product Name:1,1,3,3-TETRAMETHYLDISILAZANE
Synonyms:Silanamine, N-(dimethylsilyl)-1,1-dimethyl-;1,1,3,3-TETRAMETHYLDISILAZANE;N-(dimethylsilyl)-1,1-dimethylsilylamine;TETRAMETHYLDISILAZANE 98+%;1,1,3,3-Tetramethyl-2-azatrisilane;Disilazane, 1,1,3,3-tetramethyl-;N-(Dimethylsilyl)(dimethyl)silanamine;n-(dimethylsilyl)-1,1-dimethyl-silanamin
CAS:15933-59-2
MF:C4H15NSi2
MW:133.34
EINECS:240-072-2
Product Categories:Chemical Synthesis;Organometallic Reagents;Organosilicon;Analytical Chemistry;Dimethylsilylation (GC Derivatizing Reagents);GC Derivatizing Reagents;Si (Classes of Silicon Compounds);Si-H Compounds;Silazanes;Silylation (GC Derivatizing Reagents);Si-N Compounds
Mol File:15933-59-2.mol
1,1,3,3-TETRAMETHYLDISILAZANE Structure
1,1,3,3-TETRAMETHYLDISILAZANE Chemical Properties
Melting point 99-100 °C
Boiling point 99-100 °C
density 0.752 g/mL at 25 °C(lit.)
refractive index n20/D 1.404(lit.)
Fp 17 °F
storage temp. Store below +30°C.
solubility Miscible with common organic solvents.
pka9.80±0.70(Predicted)
form clear liquid
color Colorless to Almost colorless
Specific Gravity0.752
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 741869
CAS DataBase Reference15933-59-2(CAS DataBase Reference)
EPA Substance Registry SystemSilanamine, N-(dimethylsilyl)-1,1-dimethyl- (15933-59-2)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-36/37/38
Safety Statements 16-26-36
RIDADR UN 2924 3/PG 2
WGK Germany 3
10-21
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
1,1,3,3-TETRAMETHYLDISILAZANE Usage And Synthesis
Chemical PropertiesClear colorless to faintly yellow liquid
Physical propertiesbp 99–100 °C; n20 D 1.4040; d 0.752 g cm?3.
UsesTetramethyldisilazane is used as a gas chromatographic derivatizing reagent. Further, it reacts with phenol to prepare dimethylphenoxysilane. In addition, it is used in electronic, polymer and pharmaceutical industries.
Uses1,1,3,3-Tetramethyldisilazane is widely used in intramolecular hydrosilation of allyl alcohols, homoallyl alcohols, and homopropargyl alcohols for the regio- and stereoselective synthesis of polyols
1,1,3,3-TETRAMETHYLDISILAZANE Preparation Products And Raw materials
1,3-DIPHENYL-1,1,3,3-TETRAMETHYLDISILAZANE HEXAETHYL DISILAZANE (1-ETHOXYCARBONYLMETHYL)-2,2,5,5-TETRAMETHYL-1-AZA-2,5-DISILACYCLOPENTANE 1,3 BIS(3-CYANOPROPYL)TETRAMETHYLDISILAZANE BIS(TRIMETHYLSILYL)AMIDODIMETHYLPHOSPHINE 2,2,4,4,6,6-Hexamethylcyclotrisilazane NONAMETHYLSTANNASILAZANE 1,3-DIETHYL-1,1,3,3-TETRAMETHYLDISILAZANE, PURISS, 98%,1,3-DIETHYL-1,1,3,3-TETRAMETHYLDISILAZANE 97%,1,3-DIETHYL-1,1,3,3-TETRAMETHYLDISILAZANE TRIS(DIMETHYLSILYL)AMINE 1,3-DIMETHYL-1,1,3,3-TETRAPHENYLDISILAZANE 1,3-BIS(4-BIPHENYL)TETRAMETHYLDISILAZANE 1,3-DI-N-BUTYL-1,1,3,3-TETRAMETHYLDISILAZANE,1,3-DIBUTYL-1,1,3,3-TETRAMETHYLDISILAZANE,DI-N-BUTYL-1,1,3,3-TETRAMETHYLDISILAZANE 1,3-bis(Trifluoropropyl)-1,1,3,3-tetramethyldisilazan N,N-Bis(trimethylsilyl)acetamide NONAMETHYLTRISILAZANE HEPTAMETHYLDISILAZANE N,N-Bis(trimethylsilyl)formamide 1,3-DI-N-OCTYLTETRAMETHYLDISILAZANE

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