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| | 2-Vinylnaphthalene Basic information |
| Product Name: | 2-Vinylnaphthalene | | Synonyms: | (2-Naphthyl)ethylene;b-Vinylnaphthalene;2-VINYLNAPHTHALENE , STABILIZED WITH CA 0.4% 4-T-BUTYLCATECHOL;2-Vinylnaphthalene, 97%, stab. with ca 0.4% 4-tert-butylcatechol;2-Vinylnaphthalene, 97%, stabilized;2-Vinylnaphthalene, 98%, stabilized;2-Vinylnaphthalene, 97%, stab. with ca 0.4% 4-t-butylcatechol;2-Vinylnaphthalene 95% | | CAS: | 827-54-3 | | MF: | C12H10 | | MW: | 154.21 | | EINECS: | 212-573-6 | | Product Categories: | Naphthalene series;NLO MonomersPolymer Science;Non-Linear Optical (NLO) Materials;Photonic and Optical Materials;Styrene and Functionalized Styrene MonomersPolymer Science;Monomers;Polymer Science;Vinyl Halides, Amines, Amides, and Other Vinyl Monomers | | Mol File: | 827-54-3.mol |  |
| | 2-Vinylnaphthalene Chemical Properties |
| Melting point | 64-68 °C (lit.) | | Boiling point | 135 °C (18 mmHg) | | density | 1.1092 (estimate) | | refractive index | 1.4840 (estimate) | | Fp | >230 °F | | storage temp. | 2-8°C | | form | Powder | | color | White to slightly beige or yellow | | Water Solubility | INSOLUBLE | | BRN | 2038190 | | InChIKey | KXYAVSFOJVUIHT-UHFFFAOYSA-N | | CAS DataBase Reference | 827-54-3(CAS DataBase Reference) | | NIST Chemistry Reference | Naphthalene, 2-ethenyl-(827-54-3) |
| | 2-Vinylnaphthalene Usage And Synthesis |
| Chemical Properties | Tan powder | | Uses | 2-Vinylnaphthalene is employed in the synthesis of various copolymers such as Poly (sodium styrenesulfonate-co-2-vinyl-napthalene) copolymer and Poly (2-vinylnapthalene-alt-maleic acid)-graft-polystyrene. The latter finds applications as a photoactive polymer micelle and stabilizer for polystyrene latexes. | | Application | Used in plastic scintillators, neutron detectors and other demanding device applications. Poly(2-vinyl naphthalene) is synthesized by free radical or anionic living polymerization 2-vinylnaphthalene. | | Definition | ChEBI: 2-vinylnaphthalene is a vinylnaphthalene carrying a vinyl group at position 2. | | Synthesis Reference(s) | Tetrahedron Letters, 24, p. 2723, 1983 DOI: 10.1016/S0040-4039(00)88005-3 | | General Description | 2-Vinylnaphthalene (2VNP) can be prepared by the alkylation of naphthalene to I-and 2 ethylnapthalenes followed by dehydrogenation, or by oxidation followed by dehydration. 2VNP is the monomer for poly-(2-vinylnapthalene). | | Purification Methods | The flammable solid can be fractionally distilled under reduced pressure using a spinning-band column; dry it with CaH2 and again distil it under vacuum. It crystallises from aqueous MeOH, EtOH (m 66o) or pet ether (m 66-66.5o). Store it in sealed ampoules in a freezer. The picrate has m 91-92o (from EtOH). [Beilstein 5 III 1775, 5 IV 1833.] It is an irritant. |
| | 2-Vinylnaphthalene Preparation Products And Raw materials |
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