1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE

1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE Basic information
Product Name:1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE
Synonyms:alpha:,alpha:'-Bis(di-t-butylphosphino)-o-xylene, min. 97%;α,α'-bis(di-t-butylphosphino)-o-xylene;a,a'-Bis(di-t-butylphosphino)-o-xylene, min. 97%;1,2-Bis(di-t-butylphosphinoMethyl)benzene, 98%;1,2-Bis(di-t-butylphosphinoMethyl)benzene, 97+%;α,α'-Bis(di-t-butylphosphino)-o-xylene, min. 97%;α,α'-Bis(di-t-butylphosphino)-o-xylene,96%;ALPHA, ALPHA'-BIS(DI-T-BUTYLPHOSPHINO)-O-XYLENE
CAS:121954-50-5
MF:C24H44P2
MW:394.55
EINECS:
Product Categories:Polydentate Phosphine Ligands;Phosphorus Compounds;Catalysis and Inorganic Chemistry;Aryl Phosphine;Achiral Phosphine
Mol File:121954-50-5.mol
1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE Structure
1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE Chemical Properties
Melting point 59-62°C
Boiling point 456.7±38.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color white
Sensitive air sensitive
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE Usage And Synthesis
UsesDTBPMB may be used as a ligand for the palladium-catalyzed hydroesterification of styrene and vinyl acetate to form branched esters in the presence of polymeric sulfonic acids promoters.
General Description1,2-Bis(di-tert-butylphosphinomethyl)benzene (DTBPMB) is a bidentate phosphine ligand. DTBPMB in combination with Pd2(dba)3 (dba = trans,trans-dibenzylideneacetone) and a sulfonic acid can catalyze the methoxycarbonylation of ethane to form methyl propanoate.
1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE Preparation Products And Raw materials
Di-tert-butylphosphine T-BUTYLPHOSPHINE Benzene 1,3-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE 1,2-BIS(DI-TERT-BUTYLPHOSPHINOMETHYL)BENZENE

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