ChemicalBook Product Catalog Chemical Reagents Deuterated Reagents PYRIDINE-D5

PYRIDINE-D5

PYRIDINE-D5 Basic information
Product Name:PYRIDINE-D5
Synonyms:PYRIDINE-D;PYRIDINE-D5;PENTADEUTEROPYRIDINE;PYRIDINE-D7;(2H5)pyridine;PYRIDINE-D5, "100" (MIN. 99.96 ATOM% D)(CONTAINS 0.03% V/V TMS);PYRIDINE-D5, 99 ATOM % D;PYRIDINE-D5, 99 ATOM % D (1PK=10 X 1ML)
CAS:7291-22-7
MF:C5H5N
MW:79.1
EINECS:230-720-2
Product Categories:
Mol File:7291-22-7.mol
PYRIDINE-D5 Structure
PYRIDINE-D5 Chemical Properties
Melting point -41 °C
Boiling point 114.4 °C(lit.)
density 1.05 g/mL at 25 °C(lit.)
vapor pressure 26.7 hPa (25 °C)
refractive index n20/D 1.506(lit.)
Fp 68 °F
storage temp. no restrictions.
solubility 1000g/l soluble
pkapK1:5.83(+1) (25°C)
form Liquid
color Colorless
PH8.81 (H2O)
explosive limit1.8-12.4%(V)
Water Solubility Soluble in water, alcohol, ether, acetone, and benzene.
BRN 114377
CAS DataBase Reference7291-22-7(CAS DataBase Reference)
EPA Substance Registry SystemPyridine-d5 (7291-22-7)
Safety Information
Hazard Codes F,Xn,T
Risk Statements 11-20/21/22-63-43-36/37/38-23/24/25-45-65-48/23/24/25-36/38-46-52-40
Safety Statements 26-28-36/37-24/25-23-53-45
RIDADR UN 1282 3/PG 2
WGK Germany 3
F 10
Autoignition Temperature482 °C
HS Code 2845 90 10
HazardClass 3
PackingGroup II
ToxicityLD50 orally in Rabbit: 891 mg/kg LD50 dermal Rabbit 1121 mg/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
PYRIDINE-D5 Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesPyridine-d{5} is used in the synthesis complexes with cobalt(II) halides, pyridine-d5, a deuterated form of pyridine, ionic liquid matrices (ILMs).
DefinitionChEBI: Pyridine-d5 is a deuterated compound, an azaarene, a mancude organic heteromonocyclic parent, a monocyclic heteroarene and a member of pyridines.
General DescriptionPyridine-d5 is a deuterated NMR solvent useful in NMR-based research and analyses. It has been synthesized by palladium catalyzed H/D (hydrogen/deuterium) exchange reaction between pyridine vapor and heavy water. Infrared and Raman spectra of pyridine-d5 have been recorded in the range 300–4000cm-1.
PYRIDINE-D5 Preparation Products And Raw materials
Raw materialsAzoniabenzene-->1-ACETYLPYRIDINIUM-->4-Cyanopyridine-->Pyridine
Preparation ProductsPYRIDINE-2,6-D2
PYRIDINE-4-D1 PYRIDINE-2-D1 PYRIDINE-2,6-D2 PYRIDINE-D5 N-OXIDE 1,1-(4-FLUOROPHENYL)-(PYRIDINE-4-YL)-METHANOL 1-CYCLOHEXYL-5-(2-HYDROXY-BENZOYL)-2-OXO-1,2-DIHYDRO-PYRIDINE-3-CARBONITRILE 1-CHLORO-2-FORMYL-3-METHYL-BENZO[4,5]IMIDAZO[1,2-A]PYRIDINE-4-CARBONITRILE 1-BENZYL-4-(4-TERT-BUTYL-PHENYL)-1,2,3,6-TETRAHYDRO-PYRIDINE 1-BENZYL-4-METHYL-1,2,3,6-TETRAHYDRO-PYRIDINE 1-BUTYLPYRIDINIUM-D14 CHLORIDE PYRIDINE-D5 1-BENZYL-4-(4-CHLORO-PHENYL)-1,2,3,6-TETRAHYDRO-PYRIDINE 1-BENZYL-4-(4-FLUORO-PHENYL)-1,2,3,6-TETRAHYDRO-PYRIDINE 1-BENZYL-4-PHENYL-1,2,3,6-TETRAHYDRO-PYRIDINE 1-BENZYL-4-(4-ETHYL-PHENYL)-1,2,3,6-TETRAHYDRO-PYRIDINE 1-(BENZYLOXY)-2-(4-CHLOROPHENYL)-1H-IMIDAZO[4,5-B]PYRIDINE N-HEXADECYLPYRIDINIUM-D5 BROMIDE 1-CHLORO-2-(2-CHLORO-BENZYL)-3-METHYL-BENZO[4,5]IMIDAZO[1,2-A]PYRIDINE-4-CARBONITRILE
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