3-Ethynylthiophene

3-Ethynylthiophene Basic information
Uses
Product Name:3-Ethynylthiophene
Synonyms:3-ETHYNYLTHIOPHENE 96;thienylacetylene;Thiophene, 3-ethynyl- (9CI);3-Ethynylthiophene;(Thien-3-yl)acetylene;3-Thienylacethylene;Thiophene, 3-ethynyl-;3-Ethynylthiophene 96%
CAS:67237-53-0
MF:C6H4S
MW:108.16
EINECS:
Product Categories:Heterocyclic Compounds;Thiophenes;Heterocyclic Building Blocks;Building Blocks
Mol File:67237-53-0.mol
3-Ethynylthiophene Structure
3-Ethynylthiophene Chemical Properties
Boiling point 152-153 °C (lit.)
density 1.098 g/mL at 25 °C (lit.)
refractive index n20/D 1.5800(lit.)
Fp 115 °F
storage temp. Keep in dark place,Inert atmosphere,2-8°C
form Liquid
color Colorless to yellow to orange
Water Solubility Slightly soluble in water.
Safety Information
Hazard Codes Xi
Risk Statements 10-37/38-41
Safety Statements 16-26-39
RIDADR UN 1993 3/PG 3
WGK Germany 3
HazardClass 3
PackingGroup III
HS Code 29349990
MSDS Information
3-Ethynylthiophene Usage And Synthesis
Uses3-Ethynylthiophene is used in preparation of benzothiazonines by rhodium-catalyzed denitrogenative annulation reactions of sulfonylaryltriazoles with thiochromones.
Uses3-Ethynylthiophene may be used in the synthesis of the following:
  • 1-(2-bromobenzyl)-4-(thiophen-3-yl)-1H-1,2,3-triazole which is obtained by heating with 2-iodophenylethylazide in the presence of copper acetate monohydrate catalyst in N-methyl-2-pyrrolidone
  • N-benzyl-1-phenyl-5-(thiophen-3-yl)-4-pentyn-2-amine via a multi-step reaction process
  • [(C4H3S-3)C≡CAg]n, a polymeric compound obtained via reaction with silver nitrate in the presence of triethylamine in acetonitrile
  • 4,5-bis(thiophen-3-ylethynyl)phthalonitrile via Sonogashira cross-coupling reaction with 4,5-dichlorophthalonitrile
3-Ethynylthiophene Preparation Products And Raw materials
Preparation Products1,3,5-tri(thiophen-2-yl)benzene-->METHYL THIOPHENE-3-ACETATE-->3-(TRIMETHYLSILYLETHYNYL)THIOPHENE 97-->METHYL 3-THIOPHENECARBOXYLATE 97-->Imidazo[1,2-a]pyridine, 2-(3-thienyl)-
RARECHEM AN KC 0539 RARECHEM AN KD 0546 RARECHEM AL BK 0410 RARECHEM AL BI 0410 RARECHEM AL BL 0399 CHEMBRDG-BB 4015491 2-(Buta-1,3-diynyl)-5-(but-en-1-ynyl)thiophene RARECHEM AL BE 0410 Thifensulfuron RARECHEM AL BM 0410 RARECHEM AL BF 0410 RARECHEM AN KA 0546 2-((TRIMETHYLSILYL)ETHYNYL)THIOPHENE 9& RARECHEM AL BP 0410 RARECHEM AN KB 0547 Tetrahydrothiophene Cephalothin sodium RARECHEM AL BZ 0399

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