Triphenylbismuth

Triphenylbismuth Basic information

Product Name:	Triphenylbismuth
Synonyms:	BISMUTH TRIPHENYL;Triphenylbismuth,99%;Bismuthine, triphenyl-;TRIPHENYLBISMUTH;TRIPHENYLBISMUTHINE;TPB;(C6H5)3Bi;Aerotex
CAS:	603-33-8
MF:	C18H15Bi
MW:	440.29
EINECS:	210-033-4
Product Categories:	Furans;Organometallics;blocks;BuildingBlocks;organobismuth compound
Mol File:	603-33-8.mol

Triphenylbismuth Chemical Properties

Melting point	78-80 °C
Boiling point	310°C
density	1,585 g/cm³
refractive index	1.7040
Fp	242°C/14mm
storage temp.	Inert atmosphere,Room Temperature
solubility	Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form	crystal
color	white
Specific Gravity	1.585
Water Solubility	insoluble
Sensitive	Moisture Sensitive
Hydrolytic Sensitivity	4: no reaction with water under neutral conditions
CAS DataBase Reference	603-33-8(CAS DataBase Reference)
NIST Chemistry Reference	Bismuthine, triphenyl-(603-33-8)
EPA Substance Registry System	Triphenylbismuth (603-33-8)

Safety Information

Hazard Codes	Xn
Risk Statements	20/21/22
Safety Statements	24/25-36/37
WGK Germany	3
RTECS	EB2980000
TSCA	Yes
HS Code	29319090

MSDS Information

Provider	Language
Triphenylbismuth	English
ACROS	English
ALFA	English

Triphenylbismuth Usage And Synthesis

Chemical Properties	white to off-white crystalline powder
Uses	Triphenylbismuth, as an volatile organometallic used in the preparation of thin films of superconducting oxides by CVD. It is also added to the fuel of rocket as cruing agent. It acts as a solidifying catalyst for butyl hydroxyl propellants.
Purification Methods	Dissolve it in EtOH, precipitate it with H2O, extract with Et2O, dry and evaporate till the residue crystallises. It has been recrystallised from EtOH and Et2O/EtOH and is a stable compound. [Forward et al. J Chem Soc suppl p121 1949, Pfeiffer et al. Chem Ber 37 4620 1904, Gilman & Yablunky J Am Chem Soc 62 665 1940, UV: Jaffé J Chem Phys 22 1430 1954, Beilstein 4 III 1841.]

Triphenylbismuth Preparation Products And Raw materials

Raw materials	2-iodo-N,N-dimethyl-aniline-->2-AMINO-2,4,6-CYCLOHEPTATRIEN-1-ONE-->Bismuth trichloride
Preparation Products	Methyl isopropyl ether-->OSMIUM CARBONYL-->8-chloro-1-phenyl-1H-1,5-benzodiazepine-2,4(3H,5H)-dione-->4-BROMODIPHENYLMETHANE-->3-(TRIFLUOROMETHYL)BENZOPHENONE-->3-PHENYL-CYCLOHEXANONE-->4-Nitrobiphenyl-->DIPHENYL DITELLURIDE-->3-(PHENYLSULFONYL)PROPIONIC ACID-->5-PHENYL-2-FURALDEHYDE-->4-Methoxybiphenyl-->2-Bromo-6-phenylpyridine-->(4-ACETYLPHENYL)PHENYLMETHANE-->1-ADAMANTYL(PHENYL)METHANONE

Triphenyltin acetate Triphenylphosphine DICHLOROTRIS(4-TRIFLUOROMETHYLPHENYL)BISMUTH TRI-O-TOLYLBISMUTHINE BIS(ACETATO-O)TRIPHENYLBISMUTH Lactulose TRIPHENYLBISMUTH(V) DICHLORIDE,TRIPHENYLBISMUTH DICHLORIDE TRIS(2-METHOXYPHENYL)BISMUTHINE DICHLOROTRIS(2-METHOXYPHENYL)BISMUTH TRI-P-TOLYLBISMUTHINE (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Triphenylantimony Triphenylbismuth DICHLORO(TRI-O-TOLYL)BISMUTH Triphenylmethyl Chloride TRIPHENYLBISMUTH CARBONATE,TRIPHENYLBISMUTH(III) CARBONATE,[CARBONATO(2)-O]TRIPHENYLBISMUTH TRIS(4-ETHOXYPHENYL)BISMUTH 2,3,5-Triphenyltetrazolium chloride

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