5-Ethyl-2-methylpyridine

5-Ethyl-2-methylpyridine Basic information
Uses
Product Name:5-Ethyl-2-methylpyridine
Synonyms:5-ETHYL-2-METHYLPYRIDINE;FEMA NUMBER 3546;FEMA 3546;2-Methyl-5-Ethylyridine;5-ETHYL-2-METHYLPYRIDINE 97+%;2-Methyl-5-ethylpyridine (MEP);5-ETHYL-2-METHYLPYRIDINE (5-ETHYL-2-PICOLINE);5-ETHYL-2-METHYLPYRIDINE pure
CAS:104-90-5
MF:C8H11N
MW:121.18
EINECS:203-250-0
Product Categories:Pyridines derivates;Aromatics;Heterocycles;intermediate
Mol File:104-90-5.mol
5-Ethyl-2-methylpyridine Structure
5-Ethyl-2-methylpyridine Chemical Properties
Melting point -70.9 °C
Boiling point 178 °C (lit.)
density 0.919 g/mL at 25 °C (lit.)
vapor density 4.2 (vs air)
vapor pressure 1.853hPa at 20℃
FEMA 3546 | 5-ETHYL-2-METHYLPYRIDINE
refractive index n20/D 1.497(lit.)
Fp 151 °F
storage temp. Store below +30°C.
solubility 12.0g/l
pkapK1:6.51(+1) (20°C)
form clear liquid
color Colorless to Light orange to Yellow
Specific Gravity0.921 (20/4℃)
Odorat 0.10 % in propylene glycol. nutty strong raw potato roasted earthy
Odor Typenutty
Water Solubility practically insoluble
Merck 14,3844
JECFA Number1318
BRN 109269
Stability:Stable. Hygroscopic. Combustible. Incompatible with strong oxidizing agents.
InChIKeyNTSLROIKFLNUIJ-UHFFFAOYSA-N
LogP2.1 at 22℃
CAS DataBase Reference104-90-5(CAS DataBase Reference)
NIST Chemistry ReferencePyridine, 5-ethyl-2-methyl-(104-90-5)
EPA Substance Registry System5-Ethyl-2-methylpyridine (104-90-5)
Safety Information
Hazard Codes C,N
Risk Statements 20/22-34-20/21/22-52/53
Safety Statements 26-36/37/39-45-61
RIDADR UN 2300 6.1/PG 3
WGK Germany 3
RTECS TJ6825000
Hazard Note Corrosive
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29333990
Hazardous Substances Data104-90-5(Hazardous Substances Data)
MSDS Information
ProviderLanguage
2-Methyl-5-ethylpyridine English
SigmaAldrich English
ACROS English
ALFA English
5-Ethyl-2-methylpyridine Usage And Synthesis
Uses

5-Ethyl-2-methylpyridine is found in alcoholic beverages. 5-Ethyl-2-methylpyridine is present in dry red beans, cocoa, tea and whisky. 5-Ethyl-2-methylpyridine is a flavouring agent. 5-Ethyl-2-methylpyridine is one of the components that contribute to the nutty, roasted aroma in the Parmigiano-Reggiano cheese.

Chemical Properties2-Methyl-5-ethyl pyridine is a colorless liquid with a sharp, aromatic odor.
Chemical Properties5-Ethyl-2-methylpyridine has a sharp penetrating aromatic aroma.
OccurrenceReported in dry red beans, cocoa, tea, whiskey, peppermint oil, roasted and fried chicken, cocoa, coffee and cooked shrimps.
UsesPerfume composition
Uses5-Ethyl-2-methylpyridine is used as specific solvent and as intermediate for several chemical reactions. Attributes PIS available on request. Please contact us. Contact
PreparationPrepared by heating acetaldehyde ammonia in a double volume of absolute alcohol; by heating ammonia water and paraldehyde in presence of ammonium acetate.
DefinitionChEBI: 5-Ethyl-2-methylpyridine is a member of methylpyridines.
Aroma threshold valuesDetection: 19 ppb
General DescriptionA colorless to yellow liquid. Insoluble in water and more dense than water. Hence sinks in water. Contact may slightly irritate the skin, eyes, and mucous membranes. May be toxic by ingestion. Used to make other chemicals.
Air & Water ReactionsInsoluble in water.
Reactivity Profile5-Ethyl-2-methylpyridine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides. A mixture of nitric acid and methyl ethyl pyridine was placed in an autoclave and heated and stirred for 40 minutes. The emergency vent opened due to a sudden pressure rise, then an explosion occurred after about 90 seconds [Chem. Eng. News 30:3348. 1952].
HazardToxic. Corrosive and strong irritant to tis-sue.
Health HazardBreathing of vapors will cause vomiting and chest discomfort. Contact with liquid causes skin and eye burns.
Fire HazardSpecial Hazards of Combustion Products: Irritating vapors are generated when heated
Flammability and ExplosibilityNonflammable
Safety ProfilePoison by ingestion and subcutaneous routes. Moderately toxic by skin contact. iMildly toxic by inhalation. Corrosive. A severe skin and eye irritant. Flammable when exposed to heat or flame; can react vigorously with oxidizers. Potentially explosive reaction with nitric acid at 145℃/14.5 bar. To fight fire, use alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.
Potential ExposureIn manufacture of nicotinic acid, vinyl pyridine monomer; in intermediates for insecticides, germicides and textile chemicals
ShippingUN23002-Methyl-5-ethylpyridine, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
IncompatibilitiesVapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, aldehydes, acid chlorides; chloroformates, isocyanates, phenols, cresols.
Waste DisposalDissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed
Methyl 3-Hydroxy-2-ethyl-1-methylpyridine-4(1H)-one N-ethyl-6-methylpyridine-3-ethylamine N-Ethyl-6-methylpyridine-2-amine METHYL ETHYLCELLULOSE 3-[2-(1,3-Dioxo-2H-isoindole-2-yl)ethyl]-5-ethyl-6-methylpyridine-2(1H)-one 4-ETHYL-3-METHYLPYRIDINE 2-[(2-Amino-2-oxoethyl)thio]-3-cyano-6-ethyl-5-methylpyridine 2-ETHYL-6-METHYLPYRIDINE 97%,6-ETHYL-2-METHYLPYRIDINE,2-ETHYL-6-METHYLPYRIDINE,2-ETHYL-6-METHYLPYRIDINE (2-ETHYL-6-PICOLINE) 3-[(1,3-Dioxo-2H-isoindole-2-ylmethyl)amino]-5-ethyl-6-methylpyridine-2(1H)-one 3-METHYL-4-ETHYL PYRIDINE Ethyl 3-methylpyridine-4-acetate 3-[(4,7-Dimethylbenzoxazole-2-ylmethyl)amino]-5-ethyl-6-methylpyridine-2(1H)-one 3-(2-Chloroethyl)-2-methylpyrido[1,2-a]pyrimidin-4-one 4-ETHYL-2-METHYLPYRIDINE,4-ETHYL-2-METHYLPYRIDINE 95%,4-ETHYL-2-METHYLPYRIDINE (4-ETHYL-2-PICOLINE) 5-Ethyl-2-methylpyridine-3-carbaldehyde ETHYL HYDROXY PICOLINIUM LACTATE 5-(1-{2,5-dimethyl-4-[1-(6-methyl-3-pyridinyl)ethyl]phenyl}ethyl)-2-methylpyridine

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