Triphenylantimony

Triphenylantimony Basic information
Product Name:Triphenylantimony
Synonyms:Triphenyl antimonide;TriphenylantiMony(II;Triphenylstiban;riphenylantimony;Trifenylstibin;Triphenylstibane;Triphenyl-stibane;triphenyl-stibin
CAS:603-36-1
MF:C18H15Sb
MW:353.07
EINECS:210-037-6
Product Categories:organoantimony compound;Classes of Metal Compounds;Sb (Antimony) Compounds;Semimetal Compounds
Mol File:603-36-1.mol
Triphenylantimony Structure
Triphenylantimony Chemical Properties
Melting point 52-54 °C(lit.)
Boiling point 377 °C(lit.)
density 1,434 g/cm3
refractive index 1.6948
Fp >230 °F
storage temp. Store below +30°C.
solubility <0.001g/l
form crystal
color off-white
Specific Gravity1.4343
Water Solubility INSOLUBLE
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 3608108
Stability:Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference603-36-1(CAS DataBase Reference)
NIST Chemistry ReferenceStibine, triphenyl-(603-36-1)
EPA Substance Registry SystemStibine, triphenyl- (603-36-1)
Safety Information
Hazard Codes Xn,N
Risk Statements 20/22-51/53
Safety Statements 61
RIDADR UN 3467 6.1/PG 3
WGK Germany 2
RTECS WJ1400000
TSCA Yes
HazardClass 6.1(b)
PackingGroup III
HS Code 29310095
MSDS Information
ProviderLanguage
Triphenylantimony English
SigmaAldrich English
ACROS English
Triphenylantimony Usage And Synthesis
Chemical Propertiesoff-white powder
UsesStibonium salts, cocatalyst in converting trienes to aromatics and hydroaromatics, react with nitricsulfuric acid to give trinitro derivatives, polymerization inhibitor, lubricating-oil additive.
General DescriptionAtomic number of base material: 51 Antimony
Safety ProfilePoison by ingestion and intraperitoneal routes. Flammable when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use water, foam, mist. When heated to decomposition it emits toxic fumes of Sb. See also ANTIMONY COMPOUNDS.
Purification MethodsRecrystallise Ph3Sb from acetonitrile [Hayes et al. J Am Chem Soc 107 1346 1985]. [Beilstein 16 H 891, 16 IV 1198.]
Triphenylantimony Preparation Products And Raw materials
Preparation ProductsCeftazidiMe-->Sucralose-->Doxifluridine-->Propofol
TRIPHENYLANTIMONY DIBENZOATE TRIPHENYLANTIMONY DIBROMIDE TRIPHENYLANTIMONY SULFIDE Lactulose Diantimony trioxide triphenylantimony(v) dichloride,TRIPHENYLANTIMONY DICHLORIDE TETRAPHENYLANTIMONY(V) METHOXIDE (Trifluoromethoxy)benzene Triphenyltin acetate Antimony trichloride (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Phloroglucinol dihydrate Triphenylantimony Antimony trifluoride Triphenylmethyl Chloride Triphenylphosphine Tamoxifen 2,3,5-Triphenyltetrazolium chloride

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