Sodium diethyldithiocarbamate trihydrate

Sodium diethyldithiocarbamate trihydrate Basic information
Product Name:Sodium diethyldithiocarbamate trihydrate
Synonyms:SODIUM DIETHYLDITHIOCARBAMATE TRIHYDRATE;SODIUM DIETHYLDITHIOCARBAMATE 3H2O;SODIUM N,N'-DIETHYLDITHIOCARBAMATE TRIHYDRATE;SODIUM N,N-DIETHYLDITHIOCARBAMATE TRIHYDRATE;SODIUM ETHYLDITHIOCARBAMATE;CUPRAL;CUPRAL SODIUM SALT TRIHYDRATE;DIETHYLDITHIOCARBAMIC ACID SODIUM SALT TRIHYDRATE
CAS:20624-25-3
MF:C5H14NNaOS2
MW:191.28
EINECS:677-810-1
Product Categories:Building Blocks;Chemical Synthesis;Aliphatics;Organic Building Blocks;Sulfur Compounds;Thiocarbonyl Compounds;Amines;Inhibitors
Mol File:20624-25-3.mol
Sodium diethyldithiocarbamate trihydrate Structure
Sodium diethyldithiocarbamate trihydrate Chemical Properties
Melting point 95-98.5 °C(lit.)
density 1.100
vapor density 5.9 (vs air)
storage temp. room temp
solubility H2O: passes test
form Crystals or Powder
color White to off-white
PH7 (20g/l, H2O, 20℃)
OdorOdorless
PH Range11.6
Water Solubility FREELY SOLUBLE
Sensitive Hygroscopic
Merck 14,3378
BRN 3920507
Stability:Stable. Incompatible with strong oxidizing agents. Hygroscopic.
CAS DataBase Reference20624-25-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-38-41-36/37/38
Safety Statements 26-39-37/39-36
RIDADR UN 3077 9 / PGIII
WGK Germany 3
RTECS EZ6550000
TSCA Yes
HS Code 29302000
ToxicityLD50 orally in Rabbit: 1500 mg/kg LD50 dermal Rat > 1000 mg/kg
MSDS Information
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Diethyldithiocarbamic acid sodium salt trihydrate English
ACROS English
SigmaAldrich English
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Sodium diethyldithiocarbamate trihydrate Usage And Synthesis
Chemical Propertieswhite to light yellow crystals
UsesA possible nuclear factor kappa B inhibitor.
UsesSpin trap used in conjunction with Fe2+ to detect NO in brain, kidney, liver, and other tissues. Simultaneous direct measurement of NO* and pO2 has been reported. Sodium diethyldithiocarbamate trihydrate is a copper chelator, it has been used to quantitate copper in biological materials by ESR and is an inhibitor of superoxide dismutase, ascorbate oxidase, and other enzymes.
UsesSodium diethyldithiocarbamate trihydrate is a spin trapping reagent used in conjunction with ferrous ion to detect nitric oxide in brain, kidney, liver and other tissues. It is used as sensitive reagent for the determination of copper, rubber vulcanization accelerator and finds application in the determination of other metals such as zinc, cobalt, platinum and palladium. Furthermore, it is an inhibitor of superoxide dismutase, ascorbate oxidase and other enzymes as well as inhibits the induction of macrophage nitric oxide synthase.
General DescriptionSodium diethyldithiocarbamate trihydrate may be used:
  • To synthesize cis-dichlorobis(N,N-diethyldithiocarbamato) tin(IV) by reacting with tin(II) chloride.
  • As an alternative to xanthates to generate carbamoyl radical precursors.
  • To synthesize a soluble precursor polymer for poly(thienylene vinylene).
  • To synthesize dichlorotetrakis(dimethyl sulfoxide)ruthenium (II), which can be a precursor to prepare other ruthenium complexes.[17}

Biochem/physiol ActionsInhibits induction of macrophage nitric oxide synthase.
Purification MethodsRecrystallise it from water. [Beilstein 4 III 224, 4 IV 390.]
Sodium diethyldithiocarbamate trihydrate Preparation Products And Raw materials
S-SODIUM ETHANETHIOSULFONATE Sodium diethyldithiocarbamate Sodium benzoate SILVER DIETHYLDITHIOCARBAMATE DibutylCarbamodithioic acid sodium salt sodium Dithiooxamide Trisodium phosphate Diclofenac sodium Sodium diethyldithiocarbamate trihydrate Sodium formate Sodium citrate Sodium bicarbonate Sodium hydroxide Sodium thiosulfate pentahydrate Sodium chlorite 8-CHLOROADENOSINE-3',5'-CYCLIC MONOPHOSPHOROTHIOATE, RP-ISOMER SODIUM SALT Diethyl disulfide

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