ChemicalBook Product Catalog Chemical Reagents Organic reagents Tricyclic compound 9,10-DICYANOANTHRACENE

9,10-DICYANOANTHRACENE

9,10-DICYANOANTHRACENE Basic information
Product Name:9,10-DICYANOANTHRACENE
Synonyms:9,10-Dicyanoanthracen;RARECHEM AQ BD AN07;9,10-Anthracenedicarbonitrile,99%;9,10-DICYANOANTHRACENE;9,10-ANTHRACENEDICARBONITRILE;ANTHRACENE-9,10-DICARBONITRILE;DCA;DCAsensitizer
CAS:1217-45-4
MF:C16H8N2
MW:228.25
EINECS:
Product Categories:Aromatic Nitriles;Anthracenes
Mol File:1217-45-4.mol
9,10-DICYANOANTHRACENE Structure
9,10-DICYANOANTHRACENE Chemical Properties
Melting point 340 °C(lit.)
Boiling point 360.06°C (rough estimate)
density 1.2027 (rough estimate)
refractive index 1.5635 (estimate)
storage temp. Sealed in dry,Room Temperature
form powder to crystal
color Light yellow to Yellow
BRN 1646384
CAS DataBase Reference1217-45-4(CAS DataBase Reference)
EPA Substance Registry System9,10-Anthracenedicarbonitrile (1217-45-4)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 22-24/25
RIDADR 3439
WGK Germany 3
HazardClass 6.1
PackingGroup III
HS Code 29269095
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
9,10-DICYANOANTHRACENE Usage And Synthesis
Chemical PropertiesYELLOW TO GOLDEN YELLOW NEEDLES OR POWDER
Uses9,10-Anthracenedicarbonitrile may be used as photosensitizer to investigate the photoisomerization of trans-stilbene (TS) in sodium dodecyl sulfate (SDS)/benzyl alcohol (BA)/H2O system.
DefinitionChEBI: An anthracenedinitrile carrying cyano groups at positions 9 and 10.
General Description9,10-Anthracenedicarbonitrile (DCA, ADC) is an anthracene derivative. Photochemical reactions of DCA in MeCN-MeOH or MeCN-H2O containing hydroxides or methoxides affords 9-methylimino-10-anthracenecarbonitrile. It participates in the generation of nucleophilic α-hydroxymethyl radicals from α-silyl ethers by irradiation. Binding energy of 9,10-anthracenedicarbonitrile adsorbed onto graphene is -1.23eV.
Purification MethodsRecrystallise the dinitrile twice from pyridine [Mattes & Farid J Am Chem Soc 108 7356 1986]. [Beilstein 9 IV 3667.]
9,10-DICYANOANTHRACENE Preparation Products And Raw materials
Raw materials1,2,4,5-TETRAMETHYLBENZENE-D14-->9-Anthrracenecarbonitrile-->HEXAMETHYLBENZENE-D18-->HEXAMETHYLBENZENE-->9,10-Dibromoanthracene
DDQ 9,10-dibroMo-2,6-di-tert-butylanthracene 9,10-DibromoPhenanthrene 9,10-DIMETHYLANTHRACENE 9-Anthrracenecarbonitrile 1,4-DICYANONAPHTHALENE 1-Cyanonaphthalene 9,10-DICYANOANTHRACENE; DCA; DCA (SENSITIZER) 1-CYANO-4-METHYLNAPHTHALENE 1,4-DIMETHYLNAPHTHALENE 1,4-Dicyanobenzene 9,10-DICYANOANTHRACENE p-Tolunitrile 9-METHYLANTHRACENE
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