ChemicalBook Product Catalog Organic Chemistry Heterocyclic Compounds (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE

(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Basic information
Reaction
Product Name:(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
Synonyms:2,6-Bis[(4S)-4-isopropyl-2-oxazolin-2-yl]pyridine;2,6-Bis((S);-4-isopropyl-4,5-dihydrooxazol-2-yl);2,6-Bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine,99%e.e.;(-)-2,6-BIS[(4S)-4-(I-PROPYL)-2-OXAZOLIN-2-YL]PYRIDINE;2,6-BIS[(4S)-(-)-ISOPROPYL-2-OXAZOLIN-2-YL]PYRIDINE;2,6-Bis[(4S)-(-)-isopropyl-2-oxazolin-2-yl]pyridine ,99%;(S,S)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-ISOPROPYL-2-OXAZOLINE)
CAS:118949-61-4
MF:C17H23N3O2
MW:301.38
EINECS:
Product Categories:organic amine;BOX series;Asymmetric Synthesis;Synthetic Organic Chemistry;Chiral Nitrogen
Mol File:118949-61-4.mol
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Structure
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Chemical Properties
Melting point 155-157 °C(lit.)
alpha -120° (c 1.0, CH2Cl2)
Boiling point 457.1±30.0 °C(Predicted)
density 1.23±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,2-8°C
pka3.78±0.70(Predicted)
form crystal
color white
optical activity[α]25/D 118°, c = 0.7 in methylene chloride
BRN 5824976
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29309090
MSDS Information
ProviderLanguage
SigmaAldrich English
(S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE Usage And Synthesis
Reaction
  1. Ligand used in the dual-catalyst system for highly enantioselective conjugate cyanation of unsaturated imides.
  2. Ligand for cross-coupling reactions of iodoalkanes with alkyl zinc halides.
  3. Ligand for asymmetric 1,4-addition reactions of 1,3-dicarbonyl compounds to nitroalkenes.
  4. Ligand for asymmetric allylation of aldehydes with b-carbonyl allylstannanes.
  5. Ligand used in the enantioselective Negishi reaction of racemic secondary benzylic halides.
  6. Ligand for osmium catalyzed enantioselective transfer hydrogenation.
Reactions of 118949-61-4_1
Reactions of 118949-61-4_2
Chemical PropertiesWhite powder or crystal or chunks
UsesUsed as a ligand to prepare novel ruthenium-pyridine-carboxylate complexes as new catalytic systems for alkene epoxidation.
2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine (S)-5-CF3-pyrox-tBu 2,6-Bis[(4S)-4-tert-butyloxazolin-2-yl]pyridine 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE 2,6-bis[(4S,5S)-4,5-dihydro-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine (R,R)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE (S,S)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE 2,6-BIS[(4R)-4-TERT-BUTYL-2-OXAZOLIN-2YL]PYRIDINE 2-[(4R)-4,5-dihydro-4-(phenylMethyl)-2-oxazolyl]- Pyridine 2,6-BIS(2-BENZIMIDAZOLYL)PYRIDINE (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine PYRIDINE-2-CARBOXIMIDIC ACID ETHYL ESTER (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE 2,6-Pyridinedimethanol METHYL PICOLINIMIDATE (S,S)-2,6-BIS(4-ISOPROPYL-2-OXAZOLIN-2-YL)PYRIDINE
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