ChemicalBook Product Catalog Organic Chemistry Phosphines BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)

BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)

BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) Basic information
Reaction
Product Name:BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
Synonyms:BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I);TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) BROMI DE;99.95%(metalsbasis),Rh10.1%min;BROMO-TRIS-(TRIPHENYLPHOSPHINO)RHODIUM;orange crystal;Bromotris(triphenylphosphine)rhodium(I), 99.95% (metals basis), Rh 10.1% min;rhodium(I) tris(triphenylphosphine) bromide;bromotris(triphenylphosphine)rhodium
CAS:14973-89-8
MF:C54H45BrP3Rh
MW:969.67
EINECS:239-050-5
Product Categories:Rh;chemical reaction,pharm,electronic,materials
Mol File:14973-89-8.mol
BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) Structure
BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) Chemical Properties
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Soluble in chlorinated solvents
form Crystalline
Sensitive Air sensitive
Exposure limitsACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 36
MSDS Information
ProviderLanguage
ALFA English
BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) Usage And Synthesis
Reaction
  1. Rhodium-catalyzed regio- and stereoselective addition of diphenylphosphine oxide to alkynes.
  2. Rhodium- catalyzed hydrophosphinylation.
Reactions of 14973-89-8
Chemical Propertiesorange crystals
BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) Preparation Products And Raw materials
Raw materialsTriphenylphosphine-->Lithium bromide
TRIPHENYLPHOSPHINE DIBROMIDE Rhodium(III) Chloride (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) Triphenylphosphine Triphenylphosphine hydrobromide Rhodium
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