BISMUTH GERMANIUM OXIDE

BISMUTH GERMANIUM OXIDE Basic information
Product Name:BISMUTH GERMANIUM OXIDE
Synonyms:bismuthgermaniumoxide(bi4ge3o12);tetrabismuth triacontagermanium dodecaoxide;Puratronic99.9995%(metalsbasis);bismuth germanium oxide, puratronic;BISMUTH GERMANATE;BISMUTH GERMANIUM OXIDE;Bismuth germanium oxide, Puratronic(R), 99.9995% (metals basis);Bismuth germanium oxide, Puratronic, 99.9995% (metals basis)
CAS:12233-56-6
MF:Bi4Ge3O12
MW:1245.83
EINECS:235-457-7
Product Categories:
Mol File:12233-56-6.mol
BISMUTH GERMANIUM OXIDE Structure
BISMUTH GERMANIUM OXIDE Chemical Properties
Melting point ~1050°
density 7.13
refractive index n550 2.1204; n600 2.1058; n750 2.0786
form Powder
color White
Specific Gravity7.13
Water Solubility Insoluble in water.
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
EPA Substance Registry SystemBismuth germanium oxide (Bi4Ge3O12) (12233-56-6)
Safety Information
TSCA Yes
MSDS Information
ProviderLanguage
ALFA English
BISMUTH GERMANIUM OXIDE Usage And Synthesis
DescriptionBismuth germanate is a cubic crystal with the formula, Bi4Ge3O12. It has the “evlitine” structure. A less common composition is Bi12GeO20 .
The unit cell consists of three GeO3 tetraheda arranged in a building block. These units are arranged in a cubic close-packed structure as shown in the above diagram. The crystal structure of tetrabismuth tris(germanate), Bi4Ge3O12 (I3d, Z =4), is stable to at least 7.30 GPa, as demonstrated by hydrostatic single-crystal XRD measurements in a diamond anvil cell at room temperature.
Chemical Propertieswhite chips or powder(s), 99.99995% purity [ALF93]
UsesScintillator crystal in nuclear physics, high-energy physics, geology, and nuclear medical imaging applications including PET, X-ray CT and positron CT; in electromagnetic calorimeters.
UsesBismuth germanate is used in detectors in particle physics, aerospace physics, nuclear medicine, geology exploration, and other industries. Bismuth germanate arrays are used for gamma pulse spectroscopy. BGO crystals are also used in detectors for positron emission tomography. Bismuth germanate has a high “electrooptic coefficient” (3.3 pm/V for Bi12GeO20) making it useful in nonlinear optics for building “Pockel cells”. It can also be used for photorefractive elements useful in the ultraviolet part of the electromagnetic spectrum.
UsesBismuth germanium oxide is used as an organic chemical synthesis intermediate.
BISMUTH GERMANIUM OXIDE Preparation Products And Raw materials
BISMUTH MOLYBDATE Strontium germanate MAGNESIUM GERMANATE LITHIUM NIOBATE Decanoic acid PETROLEUM ETHER CERIUM Sodium iodide GADOLINIUM Acetaldehyde LANTHANUM CHLORIDE HEPTAHYDRATE CADMIUM Bismuth nitrate Cesium iodide BISMUTH HYDROXIDE GERMANIUM MONOXIDE Germanium oxide BISMUTH GERMANIUM OXIDE

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