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| | Tetrafluoro-1-propanol Basic information |
| Product Name: | Tetrafluoro-1-propanol | | Synonyms: | 1,1,3H-perfluoropropanol;1,1,3-Trihydroperfluoro-1-propanol;1-Propanol, 2,2,3,3-tetrafluoro-;2,2,3,3-tetrafluoro-1-propano;2,2,3,3-Tetrafluoro-propanol-1;2,2,3,3-Tetrafluoropropyl alcohol;1-Hydroxy-2,2,3,3-tetrafluoropropane;Tetrafluoropropyl alcohol | | CAS: | 76-37-9 | | MF: | C3H4F4O | | MW: | 132.06 | | EINECS: | 200-955-5 | | Product Categories: | Small molecule;Organic Fluorides;Industrial/Fine Chemicals;Alcohols;C2 to C6;Oxygen Compounds;Building Blocks;C2 to C6;Chemical Synthesis;Difluoromethyl;Fluorinated Building Blocks;Organic Building Blocks;Organic Fluorinated Building Blocks;Oxygen Compounds | | Mol File: | 76-37-9.mol |  |
| | Tetrafluoro-1-propanol Chemical Properties |
| Melting point | -15°C | | Boiling point | 109 °C | | density | 1.48 g/mL at 20 °C(lit.) | | refractive index | n20/D 1.321(lit.) | | Fp | 110 °F | | storage temp. | Sealed in dry,2-8°C | | pka | 13.05±0.10(Predicted) | | form | Liquid | | color | Clear colorless | | Specific Gravity | 1.481.471 | | Water Solubility | Soluble in water. | | Merck | 14,9206 | | BRN | 1738264 | | Stability: | Stable. Flammable. Incompatible with strong oxidizing agents, strong bases, sodium, potassium, acid chlorides, acid anhydrides. | | CAS DataBase Reference | 76-37-9(CAS DataBase Reference) | | NIST Chemistry Reference | 2,2,3,3-Tetrafluoro-1-propanol(76-37-9) | | EPA Substance Registry System | 1-Propanol, 2,2,3,3-tetrafluoro- (76-37-9) |
| | Tetrafluoro-1-propanol Usage And Synthesis |
| Chemical Properties | colourless liquid | | Uses | 2,2,3,3-Tetrafluoro-1-propanol, is used as an essential fluorinated fine chemical, the main application of TFP is as a dye solvent in CD-R(W) and DVD-R(W) industry. It is also used in making textile treatment agent and pharmaceuticals. This chemical is an ideal replacement for Freon 22 detergent. | | General Description | 2,2,3,3-Tetrafluoro-1-propanol (TFP) is extensively used as the solvent. Mineralization and defluoridation of TFP by UV oxidation in a novel three-phase fluidized bed reactor was reported. Desorption of activated carbon loaded with TFP by supercritical carbon dioxide in a rotating packed bed was investigated. | | Purification Methods | Tetrafluoro-1-propanol (450mL) is added to a solution of 2.25g of NaHSO3 in 90mL of water, shaken vigorously and set aside for 24hours. The fraction distilling at or above 99o is refluxed for 4hours with 5-6g of KOH and rapidly distilled, followed by a final fractional distillation. [Kosower & Wu J Am Chem Soc 83 3142 1961.] Alternatively, shake the alcohol with alumina for 24hours, dry it overnight with anhydrous K2CO3 and distil it, taking the middle fraction (b 107-108o). [Beilstein 1 IV 2438.] |
| | Tetrafluoro-1-propanol Preparation Products And Raw materials |
| Raw materials | Propanal, 2,2,3,3-tetrafluoro--->Phosphonic acid, bis(2,2,3,3-tetrafluoropropyl) ester-->2,2,3,3,4,4,5,5-Octafluoro-1-pentanol-->5H-OCTAFLUOROPENTANAL-->Methyl 2,2,3,3-tetrafluoropropionate-->ALLYL 2,2,3,3-TETRAFLUOROPROPYL ETHER-->TRIFLUOROACETALDEHYDE | | Preparation Products | Tris(2,2,3,3-tetrafluoropropyl)phosphate-->2,2,3,3-TETRAFLUOROPROPYL ACRYLATE-->1H,1H,2'H,3H-DECAFLUORODIPROPYL ETHER-->1,2-BENZENEDICARBONITRILE, 4-(2,2,3,3-TETRAFLUOROPROPOXY)-->1,1,2,2-tetrafluoro-3-(vinyloxy)propane-->1,1,2,2-Tetrafluoroethyl-2,2,3,3-tetrafluoropropylether |
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