CHLORDIMEFORM

CHLORDIMEFORM Basic information
Product Name:CHLORDIMEFORM
Synonyms:Chlorfenamidine;chlorodimeform(newzealand);Chlorophenamidin;Chlorphenamidine;Ciba 8514;ciba-8514;Ciba-C8514;ENT 27567
CAS:6164-98-3
MF:C10H13ClN2
MW:196.68
EINECS:228-200-5
Product Categories:Pesticides;Pesticides&Metabolites;FormamidesMethod Specific;AcaricidesAlphabetic;C;CHPesticides;Insecticides;Oeko-Tex Standard 100
Mol File:6164-98-3.mol
CHLORDIMEFORM Structure
CHLORDIMEFORM Chemical Properties
Melting point 35°
Boiling point 293℃
density 1.05
refractive index nD25 1.5885
Fp 131℃
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
pka7.89±0.50(Predicted)
form neat
Water Solubility 0.27g/L(20 ºC)
Merck 13,2100
BRN 9256367
IARC3 (Vol. 30, Sup 7) 1987
EPA Substance Registry SystemChlordimeform (6164-98-3)
Safety Information
Hazard Codes Xn,N
Risk Statements 21/22-40-50/53
Safety Statements 22-36/37-60-61
RIDADR 2761
WGK Germany 1
RTECS LQ4375000
HazardClass 6.1(b)
PackingGroup III
HS Code 29252100
Hazardous Substances Data6164-98-3(Hazardous Substances Data)
ToxicityLD50 i.p. in rats: 238 mg/kg (Robinson, Smith)
MSDS Information
CHLORDIMEFORM Usage And Synthesis
UsesBroad-spectrum acaricide used against adult mites, eggs and larvae. Also used as an insecticide against cockroaches, cotton bollworm, cotton budworm, and other pests.
UsesAcaricide, insecticide.
DefinitionOvicide, insecticide, and miticide designed for use on cotton and vegetable crops. Available in a concentrated emulsion form, it is stated to be less toxic than organophosphates and is biodegradable.
HazardQuestionable carcinogen.
Safety ProfilePoison by ingestion, skin contact, and intraperitoneal routes. Experimental reproductive effects. Human mutation data reported. An eye irritant. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits very toxic fumes of NOx and Cl-.
Environmental FatePlant. Principal soil and/or plants metabolites are p-chloro-o-toluidine, N′-(4-chloroo-tolyl)-N-methylformamidine (desmethylchlorphenamidine) and N-formyl-p-chloro-otoluidine (Verschueren, 1983). p-Chloro-o-toluidine, N′-(4-chloro-o-tolyl)-N-methylformamidine (desmethylchlor phenamidine) and N-formyl-p-chloro-o-toluidine were identified in rice grains and straws at concentrations of 3–61, 0.2–1, 10–38 and 80–6,900, 10–180, 67–500 ppb, respectively (Iizuka and Masuda, 1979).
Witkonton and Ercegovich (1972) studied the transformation of chlordimeform in six different fruits following foliar spray application. They found 4′-chloro-o-formotoluidide was the only major metabolite identified in apples, pears, cherries, plums, strawberries and peaches.
Chemical/Physical. Reacts with acids forming soluble salts (Hartley and Kidd, 1987).
Emits toxic fumes of nitrogen oxides and chlorine when heated to decomposition (Sax and Lewis, 1987).


CHLORDIMEFORM Preparation Products And Raw materials
Raw materialsThionyl chloride-->Tosyl chloride-->o-Toluidine-->4-CHLORO-2-METHYLACETANILIDE
Molosultap Phoxim N,N-didemethylchlordimeform CHLORDIMEFORM-ETHYL N,N-dimethyl-N'-o-tolylformamidine N-(4-Chloro-2-tolyl)-Nˊ,Nˊ-dimethylformamidine-14C hydrochloride Pyrrolidine, 2-((4-chloro-2-(trifluoromethyl)phenyl)imino)-1-(2,3-dich loro-2-propenyl)- CHLORDIMEFORM SOLUTION 100UG/ML IN ACETONITRILE 1ML N,N-DIMETHYL-N'-PHENYLFORMAMIDINE CHLORDIMEFORM HCL Benzenamine, 4-chloro-N-(1-(3-chloro-2-propenyl)-2-pyrrolidinylidene)- 2-methyl- demethylchlordimeform CHLORDIMEFORM CHLORDIMEFORM SOLUTION 100UG/ML IN TOLUENE 1ML

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