TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE

TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE Basic information
Uses
Product Name:TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE
Synonyms:tris(2,2’-bipyridine-n,n’)-,dichloride,hexahydrate,(oc-6-11)-ruthenium(2+;tris(2,2’-bipyridyl)ruthenium;Tris(2,2'-bipyridine)ruthenium(II) chloride hexahydrate;Tris(2,2'-bipyridyl)ruthenium(II)chloridehexahydrate,min.98%;TRIS(2,2'-BIPYRIDYL)DICHLORORUTHENIUM(II)HEXAHYDRATE, POWDER;TRIS(2,2'-BIPYRIDYL)DICHLORORUTHENIUM(II) HEXAHYDRATE, 99.95%;TRIS(2,2-BIPYRIDYL)RUTHENIUM (II) CHLORIDE HEXAHYDRATE 98+%;TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE 6-HYDRATE
CAS:50525-27-4
MF:C30H26ClN6ORu+
MW:623.1
EINECS:238-266-7
Product Categories:Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Electronic Chemicals;Transition Metal Compounds;Ru;OLED
Mol File:50525-27-4.mol
TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE Structure
TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE Chemical Properties
Melting point >300 °C(lit.)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form powder
color Red-orange to red
Water Solubility Soluble in water.
Stability:Stable, but may discolour upon exposure to light. Incompatible with strong oxidizing agents.
CAS DataBase Reference50525-27-4(CAS DataBase Reference)
Safety Information
Risk Statements 36/38
Safety Statements 22-24/25
WGK Germany 3
RTECS VM2730000
8-10
TSCA Yes
HS Code 28439000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE Usage And Synthesis
Uses

Tris (2,2’-bipyridyl) dichlororuthenium hexahydrate (RTDP, Ru (BPY) 3) is an oxygen-sensitive fluorescent stain. It can be used to measure the oxygen concentration of microfluidic chips. 
Tris(2,2'-bipyridine)dichlororuthenium(II) hexahydrate is a catalyst used in light-induced redox reactions, and is an important catalyst in studies towards photochemical water splitting. This product is widely applied in fields of photoelectrical chemical components, photovoltaic cells, smart biosensors.

Chemical Propertiesred to orange powder or crystals
Usessuzuki reaction
UsesTris(2,2'-bipyridine)dichlororuthenium(II) hexahydrate is a catalyst used in light-induced redox reactions. It is an important catalyst in studies towards photochemical water splitting. This product can be used as a catalyst in pharmaceutical research. It is widely applied in fields of photoelectrical chemical components, photovoltaic cells, smart biosensors.
General DescriptionTris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate is a metal complex and is used as an luminescent dye. The metal complex in its ground state can be excited by visible light which leads to the formation of a spin-allowed excited state. This excited state undergoes radiationless deactivation very quickly to form spin-forbidden, long-lived luminescent excited state. It is used widely in electroluminescent devices.
Purification MethodsRecrystallise it from water, then from MeOH [Ikezawa et al. J Am Chem Soc 108 1589 1986].
TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE Preparation Products And Raw materials
Raw materialsN,N-Dimethylformamide-->2,2'-Bipyridine-->Hypophosphorous acid-->Ruthenium(III) chloride hydrate(1:x)-->Tetrabutyl ammonium chloride
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Rhodium(III) 2,4-pentanedionate Tris(triphenylphosphine)rhodiu Ruthenium(II) chloride mesitylene dimer Rhodium(II) acetate dimer Dichloro(p-cymene)ruthenium(II) dimer [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Tris(triphenylphosphine)ruthenium(II) chloride [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Benzeneruthenium(II) chloride dimer Tris(2,2'-bipyridine)ruthenium dichloride Rubidium chloride 2,2'-Bipyridine 2,2'-BIPYRIDINE HYDROCHLORIDE CIS-BIS(2,2'-BIPYRIDINE)DICHLORORUTHENIUM(II) HYDRATE TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE RUBIDIUM

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