Cupric acetylacetonate

Cupric acetylacetonate Basic information
Product Name:Cupric acetylacetonate
Synonyms:COPPER(+2)ACETYLACETONATE;COPPER(II) 2,4-PENTANEDIONATE;CUPRIC(II) ACETYLACETONATE;CUPRIC AA;CUPRIC ACETYLACETONATE;BIS(ACETYLACETONATO)COPPER(II);2,4-PENTANEDIONE, COPPER(II) DERIVATIVE;ACETYLACETONE COPPER(+2)
CAS:13395-16-9
MF:C10H14CuO4
MW:261.76
EINECS:236-477-9
Product Categories:Catalysts for Organic Synthesis;Classes of Metal Compounds;Cu (Copper) Compounds;Homogeneous Catalysts;Metal Complexes;Synthetic Organic Chemistry;Organometallics;Pharmaceutical Intermediates;metal beta-diketonate complexes;proteins;Transition Metal Compounds
Mol File:13395-16-9.mol
Cupric acetylacetonate Structure
Cupric acetylacetonate Chemical Properties
Melting point 284-288 °C (dec.) (lit.)
Boiling point 160 °C (9.7513 mmHg)
density 0.721 g/cm3
vapor pressure 0.13 hPa (163 °C)
Fp 160°C/10mm
storage temp. Store below +30°C.
solubility 0.2g/l
form Crystalline Powder
color Blue to blue-grayish
Specific Gravity1.594
Water Solubility 0.2 g/L (20 ºC)
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Sublimation 160 ºC
BRN 4157957
Exposure limitsACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
Stability:Stable. Incompatible with strong oxidizing agents.
NIST Chemistry ReferenceCopper, bis(2,4-pentanedionato-o,o')-(13395-16-9)
EPA Substance Registry SystemCopper, bis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-4-1)- (13395-16-9)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36-36/37/39
WGK Germany 3
RTECS GL6520000
TSCA Yes
HS Code 29420000
Hazardous Substances Data13395-16-9(Hazardous Substances Data)
ToxicityLD50 ipr-mus: 19 mg/kg CHTHBK 16,371,71
MSDS Information
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Cupric acetylacetonate Usage And Synthesis
Chemical Propertiescrystalline solid
UsesCopper(II) acetylacetonate catalyzes coupling and carbene transfer reactions. Metal acetylacetonates are used as catalysts for polymerization of olefins and transesterification. They are used as PVC stabilizer. They are used as curing agents for epoxy resins, acrylic adhesives and silicone rubbers. They are used as solvents, lubricant additives, paint drier, and pesticides. They are used in glass coatings.
DefinitionCrystalline powder, slightly soluble in water and alcohol, soluble in chloroform, mp >230C. Resistant to hydrolysis. A chelating nonionizing compound.
Safety ProfilePoison by intravenous andintraperitoneal routes. When heated to decomposition it emits acrid smoke andfumes of Cu.
Cupric acetylacetonate Preparation Products And Raw materials
Preparation ProductsAluminum acetylacetonate
Titanium(IV)oxide acetylacetonate Thorium acetylacetonate Calcium acetylacetonate Ferrous acetylacetonate Ferric acetylacetonate COPPER(II) DIAMMONIUM CHLORIDE DIHYDRATE COPPER 1,3-DIPHENYL-1,3-PROPANEDIONATE COPPER II BENZOYLTRIFLUOROACETONATE COPPER(II) BENZOYLACETONATE COPPER(II) TRIFLUOROACETYLACETONATE 3-ACETYL-5-SEC-BUTYL-4-HYDROXY-3-PYRROLIN-2-ONE COPPER SALT COPPER(II) HEXAFLUOROACETYLACETONATE HYDRATE, 98 Cupric acetylacetonate ACETYLACETONATE COPPER(II) HEXAFLUORO-2,4-PENTANEDIONATE BIS(6,6,7,7,8,8,8-HEPTAFLUORO-2,2-DIMETHYL-3,5-OCTANEDIONATE)COPPER(II) GOLD COAST SOLUTION NO 1 copper (Ⅱ) acetylacetonate

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