ChemicalBook Product Catalog Pharmaceutical intermediates Heterocyclic compound Pyridine compound Bromopyridine 3-Bromo-2-pyridinamine

3-Bromo-2-pyridinamine

3-Bromo-2-pyridinamine Basic information
Product Name:3-Bromo-2-pyridinamine
Synonyms:3-BROMO-2-PYRIDINAMINE;3-BROMOPYRIDIN-2-AMINE;3-BROMO-PYRIDIN-2-YLAMINE;2-AMINO-3-BROMOPYRIDINE;IFLAB-BB F1371-0194;2-Pyridinamine, 3-bromo-;TIMTEC-BB SBB005538;2-AMINO-3-BROMOPYRIDINE 97%
CAS:13534-99-1
MF:C5H5BrN2
MW:173.01
EINECS:629-620-5
Product Categories:Boronic Acid;C5Heterocyclic Building Blocks;Pyridine;pharmacetical;Halogenated Heterocycles;Heterocyclic Building Blocks;Pyridine series;Pyridines
Mol File:13534-99-1.mol
3-Bromo-2-pyridinamine Structure
3-Bromo-2-pyridinamine Chemical Properties
Melting point 63-67 °C
Boiling point 232.0±20.0 °C(Predicted)
density 1.6065 (rough estimate)
vapor pressure 0.83-1.8Pa at 20-25℃
refractive index 1.5182 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka4.14±0.36(Predicted)
form Powder
color Gray to brown
BRN 109867
LogP1.5 at 20℃ and pH7
CAS DataBase Reference13534-99-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HazardClass IRRITANT
PackingGroup II
HS Code 29333990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
3-Bromo-2-pyridinamine Usage And Synthesis
Chemical Propertiesgrey to brown powder
Uses2-Amino-3-bromopyridine may be used to synthesize:
  • 2-acylamido-3-bromopyridines
  • 2-anilino-3-bromopyridine
  • 3-[(2-methoxyphenyl)ethynyl]pyridin-2-amine
  • 3-[(4-methoxyphenyl)ethynyl]pyridin-2-amine
  • N-(bromopyridyl)amidines
  • carbolines via palladium catalyzed arylation followed by palladium catalyzed amination reaction
  • 2-amino-3-cyanopyridine via palladium catalyzed cyanation reaction with potassium ferro-cyanide in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene [DBU]
  • nitro-substituted N,N′-dipyridinylamines via palladium catalyzed coupling reaction with 2-chloro-3-nitropyridine in the presence of Xantphos ligand
  • 2-amino-3-iodopyridine via reaction with sodium iodide in the presence of copper(I)iodide and trans-N,N′-dimethylcyclohexane-1,2-diamine
3-Bromo-2-pyridinamine Preparation Products And Raw materials
Preparation Products3-BROMO-5-IODOPYRIDIN-2-AMINE-->3-Bromo-2-hydroxypyridine-->3-Iodopyridin-2-amine-->3-(4-fluorophenyl)pyridin-2-ylamine-->ethyl {[(3-broMopyridin-2-yl)aMino]carbonothioyl}carbaMate-->(3-BROMO-PYRIDIN-2-YL)-METHYL-AMINE-->1H-Pyrrolo[2,3-b]pyridine-2-carboxylic acid, 3-Methyl--->8-bromo-2-(chloromethyl)imidazo[1,2-a]pyridine-->2-(PYRIDIN-2-YL)-1H-IMIDAZO[4,5-B]PYRIDINE-->N-(3-BROMO-2-PYRIDYL)BENZAMIDE-->1-Piperazinecarboxylic acid, 4-(2-aMino-3-pyridinyl)-, 1,1-diMethylethyl ester-->2-(Pyridin-3-yl)oxazolo[4,5-b]pyridine-->2-(4-METHOXY-PHENYL)-1H-PYRROLO[2,3-B]PYRIDINE
2,6-Diaminopyridine 2-Amino-3-bromo-6-methyl-5-nitropyridine ALTRENOGEST AURORA KA-375 3-Aminopyridine 2-bromopyridine 6-Aminocaproic acid Glycine 3-Bromo-2-pyridinamine 4-BROMOPYRIDINE Bromine bromo-Dragonfly 2-Aminopyridine 2-Aminophenol Tris(hydroxymethyl)aminomethane AMINO ACIDS 4-Dimethylaminopyridine 4-Aminopyridine
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