2-Bromoanisole

2-Bromoanisole Basic information

Product Name:	2-Bromoanisole
Synonyms:	1-bromo-2-methoxy-benzen;2-Bromo-1-methoxybenzene;2-Methoxybromobenzene;2-Methoxyphenyl bromide;2-methoxyphenylbromide;1-BROMO-2-METHOXYBENZENE;O-Bromoanisoles;2-BROMOANISOLE, STAB.
CAS:	578-57-4
MF:	C7H7BrO
MW:	187.03
EINECS:	209-425-8
Product Categories:	alkyl bromide;Aromatic Halides (substituted);Anisole;Miscellaneous;Anisoles, Alkyloxy Compounds & Phenylacetates;Bromine Compounds
Mol File:	578-57-4.mol

2-Bromoanisole Chemical Properties

Melting point	2 °C (lit.)
Boiling point	223 °C (lit.)
density	1.502 g/mL at 25 °C (lit.)
refractive index	n20/D 1.573(lit.)
Fp	206 °F
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	Soluble in ethanol and diethyl ether.
form	Liquid
Specific Gravity	1.502
color	Clear colorless to slightly yellow
BRN	1859996
Stability:	Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference	578-57-4(CAS DataBase Reference)
NIST Chemistry Reference	1-Bromo-2-methoxybenzene(578-57-4)
EPA Substance Registry System	Benzene, 1-bromo-2-methoxy- (578-57-4)

Safety Information

Hazard Codes	N,Xi
Risk Statements	51/53
Safety Statements	61-24/25
RIDADR	UN 3082 9/PG 3
WGK Germany	2
RTECS	BZ8500000
F	8-10-23
TSCA	T
HS Code	29093038

MSDS Information

Provider	Language
2-Bromoanisole	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Bromoanisole Usage And Synthesis

Chemical Properties	colourless liquid
Uses	2-Bromoanisole was used in the synthesis of unsymmetrically substituted biphenyl compounds. It was also used in the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3).
Uses	2-Bromoanisole was used in the synthesis of unsymmetrical substituted biphenyl compounds, used to produce (2-methoxy-phenyl)-acetone at the temperature of 100°C.
General Description	Diffusion coefficients of 2-bromoanisole at infinite dilution in supercritical carbon dioxide has been evaluated by Taylor-Aris chromatographic technique.
Purification Methods	Crystallise the anisole by repeated partial freezing, then distil it under reduced pressure. [Beilstein 6 IV 1037.]

2-Bromoanisole Preparation Products And Raw materials

Raw materials	Anisole-->5-Bromo-2-methoxybenzoic acid-->o-Anisic acid-->o-Anisidine
Preparation Products	(R,R)-DIPAMP-->2-Methoxyphenylboronic acid-->2-Bromo-4-nitroanisole-->2-Chloroanisole-->1-(2-Methoxyphenyl)piperazine hydrochloride-->2-Bromo-4-fluoroanisole-->3-BROMO-4-METHOXY-BENZENESULFONYL CHLORIDE-->2,2'-DIMETHOXYBIPHENYL-->2-METHOXYBIPHENYL-->2-(2-Methoxyphenyl)-furan-->Tributyl(2-methoxyphenyl)stannane

4',5'-DIBROMOFLUORESCEIN 3,5-DIBROMO-2-METHOXYBENZOIC ACID 3-CHLORO-4-BROMOANISOLE 3-Chloro-5-bromoanisole EOSIN METHYLENE-BLUE 5-BROMO-2,4-DIMETHOXYBENZALDEHYDE 4-Amino-2-bromoanisole 5-BROMOVERATRALDEHYDE LABOTEST-BB LT00847222 3-Bromo-5-fluoroanisole 3,5-DIBROMO-4-METHOXYBENZOIC ACID p-BROMOANISOLE pure 4-ACETOXY-3-BROMOANISOLE 2,3-Difuoro-5-Bromoanisole 3-NITRO-4-BROMOANISLOE 3-Iodo-4-Bromoanisole 3-Nitro-4-bromoanisole 2-ADAMANTANE-4-BROMOANISOLE

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