3-METHOXYCARBONYL-3-SULFOLENE

3-METHOXYCARBONYL-3-SULFOLENE Basic information
Product Name:3-METHOXYCARBONYL-3-SULFOLENE
Synonyms:Methyl 2,5-dihydrothiophene-3-carboxylate 1,1-dioxide;3-METHOXYCARBONYL-3-SULFOLENE;3-METHOXYCARBONYL-3-SULPHOLENE;3-METHOXYCARBONYL-2,5-DIHYDROTHIOPHENE-1,1-DIOXIDE;3-SULFOLENE-3-CARBOXYLIC ACID METHYL ESTER;2,5-DIHYDRO-3-METHOXYCARBONYLTHIOPHENE 1,1-DIOXIDE;3-Carbomethoxy-3-sulpholene~3-Methoxycarbonyl-2,5-dihydrothiophene-1,1-dioxide;methyl 2,5-dihydro-3-thenoate 1,1-dioxide
CAS:67488-50-0
MF:C6H8O4S
MW:176.19
EINECS:266-700-5
Product Categories:Heterocyclic Compounds
Mol File:67488-50-0.mol
3-METHOXYCARBONYL-3-SULFOLENE Structure
3-METHOXYCARBONYL-3-SULFOLENE Chemical Properties
Melting point 60-62 °C
Boiling point 360.8±42.0 °C(Predicted)
density 1.418±0.06 g/cm3(Predicted)
storage temp. 2-8°C
solubility soluble in Methanol
form powder to crystal
color White to Light yellow
BRN 1368581
CAS DataBase Reference67488-50-0(CAS DataBase Reference)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
4.10
HS Code 29349990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
3-METHOXYCARBONYL-3-SULFOLENE Usage And Synthesis
Chemical PropertiesLight yellow solid
Uses3-Methoxycarbonyl-3-sulfolene is a useful reactant for the synthesis of bicyclic and tricyclic compounds.
Purification MethodsIf the IR shows OH bands, then dissolve the dioxide in CHCl2, wash it with aqueous Na2CO3 and H2O, dry it over MgSO4, filter, evaporate and wash the residue with cold Et2O and dry in vacuo. 1HNMR (CDCl3): 7.00 (m 1H), 3.98 (bs 4H) and 3.80 (s Me). [McIntoch & Sieber J Org Chem 43 4431 1978, Beilstein 18/6 V 5.]
METHALLYL MERCAPTAN ETHYL CARBOXYETHYLSULPHONE 3-METHYL-2,5-DIHYDROTHIOPHENE-1,1-DIOXIDE 3-(ethylsulfinyl)propanoic acid 3-SULFOLENE 2,5-DIHYDROTHIOPHENE-3-CARBOXYLIC ACID METHYL ESTER 3-Methyl-2-buten-1-thiol METHOXYCARBONYLETHYL-ETHYLSULFONE 3-METHOXYCARBONYL-3-SULFOLENE METHYL-(3-HYDROXYPROPYL) SULFONE methyl 3-ethylsulfanylpropanoate 2,5-DIHYDROTHIOPHENE-3-CARBALDEHYDE

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