ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organomagnesium TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE

TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Basic information
Product Name:TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
Synonyms:TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE;(trimethylsilyl)methylmagnesium chl. sol;Trimethylsilylmethylmagnesium chloride (20% in ethyl ether;(TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE , 1.0M SOLUTION IN DIETHYL ETHER;(TRIMETHYLSILYL)METHYLMAGNESIUM CHL. SOL , 1 M IN DIETH.ETHER;[(Trimethylsilyl)methyl]magnesium Chloride 1.0 M In Diethyl Ether;[(Trimethylsilyl)methyl]magnesium Chloride, 1.0 M In Tetrahydrofuran;(Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF
CAS:13170-43-9
MF:C4H11ClMgSi
MW:146.97
EINECS:
Product Categories:Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Typical Metal Compounds;Alkyl;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Grignard Reagents;Organometallic Reagents
Mol File:13170-43-9.mol
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Structure
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Chemical Properties
Melting point 105.8-106.4 °C
density 1.04
Fp -40°C
storage temp. Flammables + water-Freezer (-20°C)e area
solubility Sol ethereal solvents; reacts with protic solvents.
form Low Melting Solid
Specific Gravity0.912
color Clear colorless to yellow to greenish
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Sensitive Air & Moisture Sensitive
BRN 3587255
CAS DataBase Reference13170-43-9(CAS DataBase Reference)
Safety Information
Hazard Codes F+,C,F
Risk Statements 12-14-22-34-66-67-19-11
Safety Statements 16-26-36/37/39-43-45
RIDADR UN 3399 4.3/PG 1
WGK Germany 1
F 10
TSCA No
HazardClass 8
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Usage And Synthesis
Chemical PropertiesGrey liquid
UsesTrimethylsilylmethylmagnesium Chloride is used in the methylenation of carbonyl compounds; provides a variety of methods to prepare allylsilanes.It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Reaction with Alkyl Halides, Reaction with Sulfur Compounds, Reaction with Other Electrophiles, Cross-coupling Reactions, Carbometalation, and as a Generator of Alkyl Radicals from Alkyl Halides in the Presence of Cobalt Catalysts etc.
UsesReagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.
PreparationFrom (chloromethyl)trimethylsilane and magnesium in an ethereal solvent.
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Preparation Products And Raw materials
Raw materialsDiethyl ether-->Magnesium-->Chloromethyltrimethylsilane
Preparation ProductsCyclohexene, 2-ethenyl-1,3,3-trimethyl--->3-methylideneoxetane
O-TOLYLMAGNESIUM BROMIDE Methylmagnesium Bromide Zinc chloride M-TOLYLMAGNESIUM CHLORIDE CYCLOPENTYLMAGNESIUM BROMIDE 2-NAPHTHYLMAGNESIUM BROMIDE 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE 2-METHOXYBENZYLMAGNESIUM CHLORIDE 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Lithium diisopropylamide 3,5-DIMETHYLPHENYLMAGNESIUM BROMIDE 3,4,5-TRIMETHOXYPHENYLMAGNESIUM BROMIDE SOLUTION 0.5M IN TETRAHYDROFURAN Magnesium monochloride TRIMETHYLSILANE DIMETHYLPHENYLSILYLMETHYLMAGNESIUM CHLORIDE DIMETHYLETHYLSILYLMETHYLMAGNESIUM CHLORIDE TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Methylmagnesium chloride
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