BENZYL GLYCIDYL ETHER

BENZYL GLYCIDYL ETHER Basic information

Product Name:	BENZYL GLYCIDYL ETHER
Synonyms:	(Benzyloxy)methyl]benzol;BENZYL GLYCIDYL ETHER;((phenylmethoxy)methyl)oxirane;(Benzyloxymethyl)oxirane;1-(benzyloxy)-2,3-epoxy-propan;Propane, 1-(benzyloxy)-2,3-epoxy-;Benzyl-2,3-epoxypropylether;VITAS-BB TBB000194
CAS:	2930-05-4
MF:	C10H12O2
MW:	164.2
EINECS:	220-899-5
Product Categories:	Oxiranes;Simple 3-Membered Ring Compounds;Epoxides;Organic Building Blocks;Oxygen Compounds
Mol File:	2930-05-4.mol

BENZYL GLYCIDYL ETHER Chemical Properties

Melting point	89.5-90.1 °C
Boiling point	70-73 °C/11 mmHg (lit.)
density	1.077 g/mL at 25 °C (lit.)
refractive index	n20/D 1.5170(lit.)
Fp	>230 °F
storage temp.	2-8°C
form	clear liquid
color	Colorless to Light yellow
InChIKey	QNYBOILAKBSWFG-UHFFFAOYSA-N
CAS DataBase Reference	2930-05-4(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-37/39
WGK Germany	3
RTECS	TX2860000
HS Code	29329990

MSDS Information

Provider	Language
SigmaAldrich	English

BENZYL GLYCIDYL ETHER Usage And Synthesis

Uses

[(Phenylmethoxy)methyl]oxirane, is a Glycidol (G615700) derivative. It is also shown that analougues of Phenyl Glycidyl Ether has in Vivo skin sensitizing potency, and is able to induce Nrf2-Dependent Luciferase Activity in the KeratinoSens.

General Description

Benzyl glycidyl ether is a glycidyl derivative. Rac-/(R)-benzyl glycidyl ether participates in the synthesis of atactic and isotactic linear poly(benzyl 1,2-glycerol carbonate)s. Biocatalytic resolution of racemic benzyl glycidyl ether by Talaromyces flavus has been described. Resolution of benzyl glycidyl ether to (S)-benzyl glycidyl ether with 30% ee and (R)-3-benzyloxypropane-1,2-diol with 40% ee by whole Bacillus alcalophilus cells has been reported. It reacts with K^-, K⁺(15-crown-5)₂to afford potassium glycidoxide and bibenzyl.

BENZYL GLYCIDYL ETHER Preparation Products And Raw materials

Raw materials	Toluene-->Chloroform-->Potassium hydroxide-->Pyridine-->Sodium Methoxide-->Benzyl chloride-->Tosyl chloride-->2,2-Dimethyl-1,3-dioxolane-4-methanol-->1,2-Propanediol, 3-(phenylmethoxy)-, 1-(4-methylbenzenesulfonate)-->(S)-2-((3-FLUOROPHENOXY)METHYL)OXIRANE-->2-((1,1’-biphenyl-4-yloxy)methyl)-oxiran-->5-PHENYL-1-PENTANOL-->6-PHENYL-1-HEXANOL-->Allyl Benzyl Ether
Preparation Products	(R)-4-BENZYLOXYMETHYL-2,2-DIMETHYL-1,3-DIOXOLANE-->1-O-BENZYL-RAC-GLYCEROL

4-O-BENZYL-1,6:2,3-DIANHYDRO-BETA-D-MANNOPYRANOSE (2S)-(+)-2-METHYLGLYCIDYL 4-NITROBENZOATE (E,E)-5-(4-CHLOROPHENYL)-1,3-DIPHENYL-2,3:4,5-DIEPOXYPENTAN-1-ONE 4-TERT-BUTYLBENZOIC ACID GLYCIDYL ESTER (2R)-(-)-GLYCIDYL 4-NITROBENZOATE (2S,3R)-(-)-3-(BENZYLOXYMETHYL)OXIRANE-2-METHANOL 4-NITROBENZOIC ACID ESTER (2S,3S)-TRANS-3-METHYLOXIRANE-2-METHYL 4-NITROBENZOATE OXYPEUCEDANIN BENZYL GLYCIDYL ETHER (2S)-(+)-GLYCIDYL 4-NITROBENZOATE Methyl2,3-Anhydro-4,6-O-benzylidene-alpha-D-mannopyranoside METHYL 2,3-ANHYDRO-4,6-O-BENZYLIDENE-ALPHA-D-ALLOPYRANOSIDE (2R)-(-)-2-METHYLGLYCIDYL 4-NITROBENZOATE (R)-(+)-Trityl glycidyl ether (S)-(+)-BENZYL GLYCIDYL ETHER,(S)-BENZYL GLYCIDYL ETHER (2R)-(+)-3 3-DIMETHYLGLYCIDYL Picroside II (R)-(-)-BENZYL GLYCIDYL ETHER, 98+%,(R)-(-)-BENZYL GLYCIDYL ETHER,(R)-BENZYL GLYCIDYL ETHER

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BENZYL GLYCIDYL ETHER

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