ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organomagnesium 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE

2-METHYL-1-PROPENYLMAGNESIUM BROMIDE

2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Basic information
Product Name:2-METHYL-1-PROPENYLMAGNESIUM BROMIDE
Synonyms:2-METHYL-1-PROPYLMAGNESIUM BROMIDE0.5M THF;2-Methyl-1-propenylmagnesium bromide, 0.5M solution in THF, AcroSeal;(2-Methylprop-1-en-1-yl)MagnesiuM broMide;2-Methyl-1-propenylmagnesium bromide 0.5M solution in THF;2-Methyl-1-propenylMagnesiuM broMide, 0.5M solution in THF, J&KSeal;(beta,beta-Dimethylvinyl)magnesium bromide;1-Bromomagnesio-2-methyl-1-propene;2,2-Dimethylvinylmagnesium bromide
CAS:38614-36-7
MF:C4H7BrMg
MW:159.31
EINECS:
Product Categories:Chemical Synthesis;Grignard Reagents;Organometallic Reagents;Alkenyl;Grignard Reagents;Organometallic Reagents;Grignard Reagent
Mol File:38614-36-7.mol
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Structure
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Chemical Properties
density 0.952 g/mL at 25 °C
Fp 5 °F
form Solution
color Yellow to dark orange
Safety Information
Hazard Codes F,C,Xn
Risk Statements 11-14/15-19-20/21/22-34-37-40-36/37/38-15
Safety Statements 16-26-27-36/37/39-45-43-36/37
RIDADR UN 3399 4.3/PG 2
WGK Germany 3
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Usage And Synthesis
Chemical PropertiesYellow to dark orange liquid
Uses2-Methyl-1-propenylmagnesium bromide can be used in a study of a palladium-catalyzed coupling with aryl tosylates.
UsesUsed in a synthesis of (2S,3S)-3′-fluoroisoleucine.
Uses2-Methyl-1-propenylmagnesium bromide(0.5?M in THF) is a reagent used in many chemical reactions such as in the preparation of biaryls, alkylarenes, alkenylarenes, alkynylalkenones via nucleophilic addition.Used in the study of palladium-catalyzed coupling with aryl tosylates.
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Preparation Products And Raw materials
Preparation ProductsCYCLOHEPTANE-->2,5-Dimethyl-2,4-hexadiene
3,5-DIFLUOROPHENYLMAGNESIUM BROMIDE 3-(Trifluoromethoxy)phenylmagnesium bromide 0.5 in THF 3-CHLOROPHENYLMAGNESIUM BROMIDE 3-BROMOBENZYLMAGNESIUM BROMIDE 4-chlorophenylmagnesium bromide 3-CHLORO-4-FLUOROPHENYLMAGNESIUM BROMID& Methylmagnesium Bromide 2,3-DIMETHYLPHENYLMAGNESIUM BROMIDE 3 4 5-TRIFLUOROPHENYLMAGNESIUM BROMIDE 1-METHYL-1-PROPENYLMAGNESIUM BROMIDE,1-Methyl-1-propenylmagnesium bromide solution,1-METHYL-1-PROPENYLMAGNESIUM BROMIDE, 0. 5M SOLUTION IN TETRAHYDROFURAN Zinc chloride 5-FLUORO-2-METHOXYPHENYLMAGNESIUM BROMIDE PHENYLETHYNYLMAGNESIUM BROMIDE 2-BROMOBENZYLMAGNESIUM BROMIDE 4-(Trifluoromethoxy)phenylmagnesium bromide 4-CHLORO-3-FLUOROPHENYLMAGNESIUM BROMIDE 1-PROPENYLMAGNESIUM BROMIDE 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE
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