Bismuth subcarbonate

Bismuth subcarbonate Basic information
Product Name:Bismuth subcarbonate
Synonyms:BISMUTH CARBONATE;BISMUTH CARBONATE, BASIC;Bismuthi Subnitras;BISMUTH CARBONATE BASIC, EXTRA PURE,DAB, PH. EUR., B. P., PH. FRANC., U. S. P.;BISMUTH(III) CARBONATE BASIC PH EUR;Bismuthcarbonateoxide,98.5%min;Bismuth (III) Carbonate Hydrate Basic;Bismuth carbonate oxide (Bi2(CO3)O2)
CAS:5892-10-4
MF:CH2BiO4(-2)
MW:287
EINECS:227-567-9
Product Categories:Inorganics
Mol File:5892-10-4.mol
Bismuth subcarbonate Structure
Bismuth subcarbonate Chemical Properties
Boiling point decomposes [CRC10]
density 6.86 g/mL at 25 °C (lit.)
solubility Practically insoluble in water and in ethanol (96 per cent). It dissolves with effervescence in mineral acids.
form Powder
color White powder
OdorOdorless
Water Solubility Practically insoluble in water, alcohol. Soluble in nitric acid, hydrochloric acid, concentrated acetic acid.Soluble in mineral acid and glacial acetic acid. Insoluble in water.
Merck 14,1282
Stability:Stable.
InChIKeyMGLUJXPJRXTKJM-UHFFFAOYSA-L
CAS DataBase Reference5892-10-4(CAS DataBase Reference)
EPA Substance Registry System2,4-Dioxa-1,5-dibismapentane, 1,3,5-trioxo- (5892-10-4)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
TSCA Yes
HS Code 2836992000
MSDS Information
ProviderLanguage
Bismuth oxycarbonate English
SigmaAldrich English
ALFA English
Bismuth subcarbonate Usage And Synthesis
Chemical PropertiesWhite Fine powder
Physical propertiesWhite powder; density 6.86 g/cm3; insoluble in water and alcohol; soluble in mineral acids.
UsesProtectant (topical).
UsesBismuth subcarbonate [(BiO)2CO3] is used to make other bismuth compounds, cosmetics, enamel, and ceramic glazes. Its major use is as an opaque substance placed in the digestive tract to show up on X-rays.
UsesOpacifier in X-ray diagnosis, enamel fluxes, ceramic glazesBismuth carbonate oxide is used in ceramic glazes and pearly coatings on plastics. It is also used as an antacid and anti-diarrheal in medicinal chemistry. Further, it is used as a filler in radiopaque catheters. It is also employed in fireworks and to make Dragon's eggs. In addition to this, it is made into nanotube arrays that exhibit antibacterial properties.
DefinitionChEBI: Bismuth subcarbonate is a bismuth coordination entity and a one-carbon compound. It is functionally related to a carbonic acid.
PreparationBismuth oxycarbonate is prepared by adding sodium carbonate to a suspension of bismuth subnitrate in water.
BiONO3 + Na2CO3 → (BiO)2CO3 + 2NaNO3
(BiO)2CO3also may be prepared by adding ammonium carbonate to a solution of bismuth salt. The nature of the product in the preparative processes depends on the nature of the subnitrate or the bismuth salt used, the amount of water and the temperature.
Flammability and ExplosibilityNotclassified
Bismuth subcarbonate Preparation Products And Raw materials
Raw materialsNitric acid-->NITRIC OXIDE-->Bismuth-->Bismuth nitrate pentahydrate-->Bismuth nitrate-->BISMUTH(III) BROMIDE
Preparation ProductsBarium carbonate
Artinite COLLOIDALBISMUTHSUBCITRATE Calcium carbonate NICKEL(II) CARBONATE BASIC HYDRATE Carbonate Cobalt(II) carbonate hydroxide Ethylene carbonate BISMUTH SUBSALICYLATE Lithium carbonate C. I. Pigment Blue 30 (77420) Bismuth subcarbonate Bismuth Lead(II) carbonate basic Bismuth nitrate oxide Zinc carbonate hydroxide Dimethyl carbonate POLY(BISPHENOL A CARBONATE) Sodium carbonate

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