MOLYBDENUM(VI) DICHLORIDE DIOXIDE

MOLYBDENUM(VI) DICHLORIDE DIOXIDE Basic information
Description Reference
Product Name:MOLYBDENUM(VI) DICHLORIDE DIOXIDE
Synonyms:Molybdenum chloride oxide;MoO2Cl2;MOLYBDENUM(VI) DICHLORIDE DIOXIDE;MOLYBDENUM DIOXY DICHLORIDE;MOLYBDENUM DICHLORIDE DIOXIDE;MOLYBDENUM DICHLORIDE OXIDE;Molybdenum dichloride dioxide, Cl 34% min;Dichlorodioxomolybdenum(VI)
CAS:13637-68-8
MF:Cl2MoO2
MW:198.84
EINECS:
Product Categories:Metal and Ceramic Science;Molybdenum Salts;Salts
Mol File:13637-68-8.mol
MOLYBDENUM(VI) DICHLORIDE DIOXIDE Structure
MOLYBDENUM(VI) DICHLORIDE DIOXIDE Chemical Properties
Melting point 184(subl.)
density 3.31 g/mL at 25 °C(lit.)
form yellow-orange solid
Safety Information
Hazard Codes C,Xi
Risk Statements 34
Safety Statements 26-27-36/37/39-45
RIDADR UN 3260 8/PG 2
WGK Germany 3
HazardClass 8
PackingGroup III
HS Code 2827499090
MSDS Information
ProviderLanguage
SigmaAldrich English
MOLYBDENUM(VI) DICHLORIDE DIOXIDE Usage And Synthesis
DescriptionMolybdenum is much less toxic than typical heavy metals and already found application as an alternative substitute for some heavy metals. Molybdenum has also found application in materials like pigments, corrosion inhibitors, smoke suppressants, lubricants and fertilizers. Molybdenum dichloride dioxide has strong application as a kind of catalyst in organic transformation. Molybdenum Dichloride Dioxide can be used to catalyze carbamate formation from an alcohol and isocyanates, acylation reactions, thioglycosylation of functionalized peracetylated glycosides, hydrosilylation of aldehydes and ketones as well as reduction of many compounds like imines, esters, amides and N-oxides. It is also used to catalyze the oxidation of sulfides, thiols as well as the synthesis of beta-keto esters and thiocaetalization of aldehydes. It can also be used to analyze the antioxidant in solder plating solutions.
Reference
  1. Stock, C., & Brückner, R. (2010) Synlett, 2010(16), 2429-2434.
  2. KING, Mackenzie, SCHOMBURG, Cory, HILGARTH, & Monica. (2005). Analysis of antioxidant in solder plating solutions using molybdenum dichloride dioxide.
  3. Jeyakumar, Kandasamy, and D. K. Chand. Journal of Chemical Sciences 121.2(2009):111-123.
Chemical Propertiesyellowish-orange solid [LID94]
UsesMolybdenum(VI) Dichloride Dioxide can be used as electrolytes for secondary lithium batteries.
MOLYBDENUM(VI) DICHLORIDE DIOXIDE Preparation Products And Raw materials
Raw materialsTrichloronitromethane-->MOLYBDENUM(V) CHLORIDE-->Molybdenum trioxide-->Chlorine-->Sodium chloride-->Hexamethyldisiloxane
Ammonium molybdate tetrahydrate Diantimony trioxide Manganese dioxide COBALT(III) OXIDE BLACK Sulfur dioxide Nickel oxide Molybdenum trioxide Molybdenum disulfide Rutile Molybdenum(IV) oxide MOLYBDENUM CHLORIDE MOLYBDENUM(VI) DICHLORIDE DIOXIDE Molybdenum

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