Copper quinolate

Copper quinolate Basic information
Product Name:Copper quinolate
Synonyms:BIS(8-QUINOLATO)COPPER(II);8-Hydroxyquinoline c;quinolin-8-ol copper;Copper quinolate W.P.;Bis(8-hydroxyquinolinato)copper(II) Copper(II) Bis(8-hydroxyquinolinate) Oxine-Copper;Copper-8-hydroxyquinoline SC;8-quinolinol,copper(ii)chelate;Bioquin 1
CAS:10380-28-6
MF:C18H12CuN2O2
MW:351.85
EINECS:233-841-9
Product Categories:INORGANIC & ORGANIC CHEMICALS;Classes of Metal Compounds;Cu (Copper) Compounds;Electroluminescence;Functional Materials;Quinolinecarboxylic Acids, etc.;Quinolines;Transition Metal Compounds;Pharmaceutical intermediates;as bactericide and agrochemical;Antibacterial agent;bc0001
Mol File:10380-28-6.mol
Copper quinolate Structure
Copper quinolate Chemical Properties
Melting point 240 °C (dec.)(lit.)
density 1,68 g/cm3
storage temp. Inert atmosphere,2-8°C
Water Solubility Insoluble in water
solubility Acidic Chloroform (Slightly), Acidic DMSO (Slightly)
form Solid
color Very Dark Grey to Black
Specific Gravity1.68
Odoryel.-grn. odorless powd. or orange clear liq., alcoholic odor
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
InChIKeyYXLXNENXOJSQEI-UHFFFAOYSA-L
LogP2.460
CAS DataBase Reference10380-28-6(CAS DataBase Reference)
IARC3 (Vol. 15, Sup 7) 1987
NIST Chemistry ReferenceCopper 8-hydroxyquinolate(10380-28-6)
EPA Substance Registry SystemCopper 8-quinolinolate (10380-28-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR 3077
WGK Germany 3
RTECS VC5250000
Hazard Note Irritant
TSCA Yes
HazardClass 9
PackingGroup III
HS Code 29334900
Toxicitymouse,LD50,intraperitoneal,67mg/kg (67mg/kg),LUNGS, THORAX, OR RESPIRATION: DYSPNEABEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLDPERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE),Toxicology and Applied Pharmacology. Vol. 5, Pg. 599, 1963.
MSDS Information
ProviderLanguage
Cupric 8-hydroxyquinolate English
SigmaAldrich English
Copper quinolate Usage And Synthesis
Chemical PropertiesYellow-green crystalline solid or powder. Odorless.
Chemical PropertiesYellow solid
Usesbis(8-Quinolinolato-κN1,κO8)-Copper is a disinfectant for vegetables. High polarity pesticide.
UsesFungicide and mildew-proofing of fabrics, analysis for copper.
HazardToxic by ingestion. Questionable carcinogen.
Potential ExposureFungicide and microbiocide.
ShippingUN3077 Environmentally Hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
IncompatibilitiesMay form highly unstable acetylides. Decomposes on burning producing toxic and corrosive fumes including copper and nitrogen oxides
Waste DisposalCopper-containing soluble wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. If recovery is not feasible, the copper can be precipitated through the use of caustics and the sludge deposited in a chemical waste landfill Copper-containing wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. Details of copper recovery from a variety of industrial wastes have been published. If recovery is not feasible, the copper can be precipitated by the use of caustics and the sludge deposited in a chemical waste landfill. Recommendable Methods: Precipitation, solidification, landfill, discharge to sewer, & incineration. Peer-review: Precipitate copper with alkali, filter, solidify precipitate. (Do not use ammonia as alkali). Cation exchange will allow recovery of copper. Eluate from cation exchanger can be passed through anion exchanger to remove (or reduce) naphthenic acid content. Exhausted ion exchange resins can be landfilled. (Peer-review conclusions of an IRPTC expert consultation)
Copper quinolate Preparation Products And Raw materials
Raw materialsSulfuric acid-->Glycerol-->Quinoline-->Cupric acetate monohydrate-->2-Aminophenol-->8-Hydroxyquinoline-->Copper(II) acetate
Preparation Products2-Hydroxyphenylacetic acid
Cupric tartrate 2-Quinolinecarboxaldehyde 6-Quinolinecarboxylic acid Triethylamine IMINOCTADINE TRIS(ALBESILATE) 8-Hydroxyquinoline sulfate Quinoxaline-5-sulfonylchloride DITHIANON Bis(8-quinolinolato) zinc 1,3-Cyclopentadiene Copper Quinoline Copper 8-quinolinolate,W.P. Copper quinolate GOLD COAST SOLUTION NO 1 Quinhydrone OXINE-COPPER Copper oxychloride

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