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Allylmagnesium chloride

Allylmagnesium chloride Basic information
Product Name:Allylmagnesium chloride
Synonyms:ALLYLMAGNESIUM CHLORIDE;ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N TETRAHYDROFURAN;ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I;ALLYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF;Allylmagnesium chloride 1.5M solution in THF;AllylMagnesiuM chloride, 1.7 M solution in THF, J&KSeal;Allylmagnesium chloride solution;Allyl chlorideMagnesiuM
CAS:2622-05-1
MF:C3H5ClMg
MW:100.83
EINECS:220-067-1
Product Categories:Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Alkyl;GRIGNARD REAGENTS;Grignard Reagents;Organometallic Reagents;Grignard Reagent
Mol File:2622-05-1.mol
Allylmagnesium chloride Structure
Allylmagnesium chloride Chemical Properties
Melting point -21°C
Boiling point 66°C
density 0.995 g/mL at 25 °C
Fp 1 °F
storage temp. water-free area
form Liquid
color Clear tan to brown, amber, dark gray, dark green or black
Water Solubility vigorous reaction
Sensitive Air & Moisture Sensitive
BRN 3587316
InChIKeyPLYLAFITHJUEGX-UHFFFAOYSA-M
EPA Substance Registry SystemMagnesium, chloro-2-propenyl- (2622-05-1)
Safety Information
Hazard Codes F,C
Risk Statements 11-14/15-34-40-37-19
Safety Statements 16-26-36/37/39-43-45-7/8-6A-43B-33
RIDADR UN 3399 4.3/PG 1
WGK Germany 1
F 1-3-10
TSCA Yes
HazardClass 4.2
PackingGroup I
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Allylmagnesium chloride Usage And Synthesis
Chemical Propertiesclear tan to brown, amber, dark grey, dark green
UsesAllylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
Grignard-reactions: reagent for the introduction of the allyl group.
UsesAllylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
ApplicationUsed in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins.
PrecautionsIt reacts violently with water.
Air & moisture sensitive.
Stable under recommended storage conditions.
Allylmagnesium chloride Preparation Products And Raw materials
Raw materialsTetrahydrofuran-->Magnesium-->Allyl chloride
Preparation Products3-METHYL-1,5-HEXADIENE-->1,6-HEPTADIEN-4-OL-->Tetraallyltin-->6-Chlorohex-1-ene-->ALLYL(DIISOPROPYL)(4-METHOXYPHENYL)SILANE-->Diallylzinc-->3-ALLYLOXETAN-3-OL
Methylene Chloride 2,3-Dichloropropene Magnesium monochloride Benzyl chloride 1.3-Dichloropropene Calcium chloride Sodium chloride 1,3-Dichloropropene PHENYLMAGNESIUM CHLORIDE TERT-BUTYLMAGNESIUM CHLORIDE Vinylmagnesium chloride Benzylmagnesium chloride ISOPROPYLMAGNESIUM CHLORIDE Choline chloride 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile Methylmagnesium chloride Allyl chloride Magnesium chloride
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