ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatic ketones 2-HYDROXYACETOPHENONE

2-HYDROXYACETOPHENONE

2-HYDROXYACETOPHENONE Basic information
Product Name:2-HYDROXYACETOPHENONE
Synonyms:2-hydroxy-1-phenyl-ethanon;2-Hydroxy-1-phenylethanone;2-Hydroxyethylphenyl ketone;Acetophenone, 2-hydroxy-;Acetophenone, alpha-hydroxy-;Ethanone, 2-hydroxy-1-phenyl-;Glycolophenone;Methanol, benzoyl-
CAS:582-24-1
MF:C8H8O2
MW:136.15
EINECS:209-480-8
Product Categories:C7 to C8;Carbonyl Compounds;Ketones
Mol File:582-24-1.mol
2-HYDROXYACETOPHENONE Structure
2-HYDROXYACETOPHENONE Chemical Properties
Melting point 86-89 °C (lit.)
Boiling point 126 °C / 12mmHg
density 1.0963
refractive index 1.5470 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
pka13.09±0.10(Predicted)
form Powder
color Slightly yellow to orange
Water Solubility Soluble in water, ether, ethanol, chloroform.
Sensitive Air & Moisture Sensitive
LogP0.721 (est)
CAS DataBase Reference582-24-1(CAS DataBase Reference)
NIST Chemistry Reference«alpha»-Hydroxyacetophenone(582-24-1)
EPA Substance Registry SystemEthanone, 2-hydroxy-1-phenyl- (582-24-1)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
TSCA Yes
HS Code 29144000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
2-HYDROXYACETOPHENONE Usage And Synthesis
Chemical Propertiesslightly yellow to orange powder
Uses2-Hydroxyacetophenone can be used to produce 2-hydroxy-1-phenyl-ethanone-(1)-oxime by heating. It is used as pharmaceutical intermediate.
Uses2-Hydroxyacetophenone can be used as a starting material for the synthesis of:
  • Enantioselective 1R-phenyl-1,2-ethanediol in the presence of a rhodium(III) catalyst by asymmetric transfer hydrogenation.
  • Copper(II) complexes of 2-hydroxyacetophenone N-substituted thiosemicarbazones.
  • Chromium, molybdenum, and ruthenium complexes of 2-hydroxyacetophenone Schiff bases.
  • 2-Hydroxyacetophenone-aroyl hydrazone derivatives for inhibition of copper corrosion in nitric acid.

DefinitionChEBI: 2-hydroxyacetophenone is a monohydroxyacetophenone that is acetophenone in which one of the methyl hydrogens has been replaced by a hydroxy group. It is a primary alcohol, a primary alpha-hydroxy ketone and a monohydroxyacetophenone.
2-HYDROXYACETOPHENONE Preparation Products And Raw materials
Preparation Products1,2-Ethanedione, 1-phenyl-2-(1-piperidinyl)- Piperidine, 1-(oxophenylacetyl)- (9CI)-->Ethyl benzoate-->2-Bromo-2′-hydroxyacetophenone-->1-Phenyl-1,2-ethanediol-->1H-Pyrazole-3-carboxylic acid, 5-(2-hydroxyphenyl)-, ethyl ester-->4-Phenyloxazole-2-thiol-->Methanesulfonic acid, 1,1,1-trifluoro-, 2-oxo-2H-1-benzopyran-4-yl ester
MORIN FISETIN HYDRATE Benzoylformic acid Ninhydrin hydrate LAPACHOL Benzoin 2-Hydroxy-1,4-naphoquinone sodium phenylglyoxylate Quercetin 3-HYDROXYFLAVONE TIMTEC-BB SBB006499 Myricetin HYDRINDANTIN ANISOIN PURPUROGALLIN (+)-TAXIFOLIN Galangin 2-HYDROXY-1-(4-METHOXYPHENYL)-1-ETHANONE
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