Tris(4-fluorophenyl)phosphine

Tris(4-fluorophenyl)phosphine Basic information
Product Name:Tris(4-fluorophenyl)phosphine
Synonyms:Phosphine, tris(p-fluorophenyl)-;TRIS(4-FLUOROPHENYL)PHOSPHINE;TRIS(P-FLUOROPHENYL)PHOSPHINE;TRI(4-FLUOROPHENYL)PHOSPHINE;Tri-(p-fluorophenyl)phosphine;Tris(4-Flurophenyl)Phosphine;Tris(4-fluorophenyl)phosphine,99%;Tris(p-fluorophenyl)phosphine,99%
CAS:18437-78-0
MF:C18H12F3P
MW:316.26
EINECS:
Product Categories:Achiral Phosphine;Aryl Phosphine;Ligand;Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds;organophosphorus ligand
Mol File:18437-78-0.mol
Tris(4-fluorophenyl)phosphine Structure
Tris(4-fluorophenyl)phosphine Chemical Properties
Melting point 79-83 °C(lit.)
Boiling point 160°C/0.1mmHg(lit.)
storage temp. Inert atmosphere,Room Temperature
form Crystalline Powder
color White to very slightly yellow
Water Solubility Insoluble in water.
Sensitive Air Sensitive
BRN 919838
InChIKeyGEPJPYNDFSOARB-UHFFFAOYSA-N
CAS DataBase Reference18437-78-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HazardClass IRRITANT
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Tris(4-fluorophenyl)phosphine Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesTris(4-fluorophenyl)phosphine (TFPP) and tris(2,2,2- trifluoroethyl) phosphite (TTFP) were used as flame-retarding additives in Li-ion battery clectrolytes.
Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.
UsesTris(4-fluorophenyl)phosphine, is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.
UsesLigand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids
Preparationwith 4-bromofluorobenzene, magnesium, and phosphorous (III) trichloride.3 Alternatively, reduction of tris(4-fluorophenyl)phosphine oxide with an iron catalyst.
General DescriptionWe are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Tris(4-fluorophenyl)phosphine Preparation Products And Raw materials
TRIS(4-FORMYLPHENYL)AMINE TRIS(2,4-DIMETHYLPHENYL)PHOSPHINE TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE TRIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE TRIS(3-METHOXYPHENYL)PHOSPHINE TRIS(4-CHLOROPHENYL)PHOSPHINE TRIS(NONYLPHENYL) PHOSPHITE Tris(4-isocyanatophenyl) thiophosphate DIPHENYL(O-TOLYL)PHOSPHINE TRIS(2-METHOXYPHENYL)PHOSPHINE TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE TRIS(4-METHOXYPHENYL)PHOSPHINE TRIS(3-FLUOROPHENYL)PHOSPHINE,Tris(3-fluorophenyl)phosphine 98%,Tris(3-fluorophenyl)phosphine98% Tris(2-carboxyethyl)phosphine hydrochloride Tris(4-fluorophenyl)phosphine sulfide,Tris(p-fluorophenyl)phosphine sulfide Tris(p-fluorophenyl)phosphine oxide TRIS(PENTAFLUOROPHENYL)PHOSPHINE Tris(p-fluorophenyl)phosphine selenide,Tris(4-fluorophenyl)phosphine selenide

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