ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Ethyl compound DIETHYL DIALLYLMALONATE

DIETHYL DIALLYLMALONATE

DIETHYL DIALLYLMALONATE Basic information
Product Name:DIETHYL DIALLYLMALONATE
Synonyms:Diethyl diallylmalonate 98%;Diethyl-2-allyl-2-butenylmalonate;Malonic acid, diallyl-, diethyl ester;Propanedioic acid, di-2-propenyl-, diethyl ester;DIALLYLMALONIC ACID DIETHYL ESTER;DIETHYL 2,2-DIALLYLMALONATE;DIETHYL DI-2-PROPENYLMALONATE;DIETHYL DIALLYLMALONATE
CAS:3195-24-2
MF:C13H20O4
MW:240.3
EINECS:221-696-4
Product Categories:monomer;Aliphatics;Esters;C12 to C63;Carbonyl Compounds
Mol File:3195-24-2.mol
DIETHYL DIALLYLMALONATE Structure
DIETHYL DIALLYLMALONATE Chemical Properties
Boiling point 128-130 °C/12 mmHg (lit.)
density 0.994 g/mL at 25 °C (lit.)
vapor pressure 4.266Pa at 25℃
refractive index n20/D 1.446(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform, DMSO, Methanol
form Oil
color Clear Colourless
Water Solubility Sparingly Soluble in water. (0.72 g/L) (25°C)
BRN 1790529
LogP3.46
CAS DataBase Reference3195-24-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 2917198090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
DIETHYL DIALLYLMALONATE Usage And Synthesis
UsesDiethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
DefinitionChEBI: Diethyl diallylmalonate is a fatty acid ester.
General DescriptionLow catalyst loading in ring-closing metathesis reaction of diethyl diallylmalonate has been reported. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
DIETHYL DIALLYLMALONATE Preparation Products And Raw materials
Preparation Products3-Cyclopentene-1-carboxylic acid ethyl ester-->Diethyl allylmalonate-->1-(Ethoxycarbonyl)-3-cyclopentene-1-carboxylic acid-->3-(1H,1H-NONAFLUOROPENTYL)-4-METHYLCYCLOPENTANE-1,1-DICARBOXYLIC ACID
2,2-DIMETHYL-MALONIC ACID DIMETHYL ESTER Dimethyl ethylmalonate 3-METHOXYISOBUTYRIC ACID METHYL ESTER Dimethyl diethylmalonate (R)-2-Hydroxymethylbutanoic acid METHYL 4-PENTENOATE 2-ETHYL-N-BUTYRIC ACID ETHYL ESTER 2-Methylpropanedioic acid 2-ETHYL-2-METHYL-1,3-PROPANEDIOL Dimethyl methylmalonate 3-ETHOXYPROPIONIC ACID SALOR-INT L165530-1EA 2-(3-ALLYL)-4-PENTEN-1-OL 2-FORMYLPROPIONIC ACID ETHYL ESTER 3-Hydroxypivalic acid 3-methoxypivalic acid (R)-(-)-3-HYDROXY-2-METHYLPROPIONIC ACID METHYL ESTER DIALLYL GLUTARATE
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