2-ISOPROPOXYETHANOL

2-ISOPROPOXYETHANOL Basic information
Product Name:2-ISOPROPOXYETHANOL
Synonyms:2-(1-methylethoxy)-ethano;2-(1-methylethoxy)-Ethanol;2-isopropoxy-ethano;beta-Hydroxyethyl isopropyl ether;beta-hydroxyethylisopropylether;Dowanal EiPAT;dowanaleipat;Dowanol EiPAT
CAS:109-59-1
MF:C5H12O2
MW:104.15
EINECS:203-685-6
Product Categories:Ethylene Glycols & Monofunctional Ethylene Glycols;Monofunctional Ethylene Glycols
Mol File:109-59-1.mol
2-ISOPROPOXYETHANOL Structure
2-ISOPROPOXYETHANOL Chemical Properties
Melting point -60 °C
Boiling point 42-44 °C13 mm Hg(lit.)
density 0.903 g/mL at 25 °C(lit.)
vapor pressure 5.99 hPa (25 °C)
refractive index n20/D 1.41(lit.)
Fp 114 °F
storage temp. Store below +30°C.
solubility >100g/l soluble
pka14.47±0.10(Predicted)
form Liquid
color Colorless to Almost colorless
explosive limit1.6-13.0%(V)
Water Solubility It is soluble in water.
BRN 1732184
Exposure limitsTLV-TWA skin 25 ppm (106 mg/m3) (ACGIH). .
Stability:Stable. Incompatible with strong oxidizing agents. Combustible.
InChIKeyHCGFUIQPSOCUHI-UHFFFAOYSA-N
LogP0.43 at 20℃
CAS DataBase Reference109-59-1(CAS DataBase Reference)
EPA Substance Registry SystemIsopropoxyethanol (109-59-1)
Safety Information
Hazard Codes Xn
Risk Statements 20/21-36
Safety Statements 24/25
RIDADR UN 2929 6.1/PG 2
WGK Germany 1
RTECS KL5075000
Autoignition Temperature240 °C
TSCA Yes
HS Code 2909 44 00
HazardClass 3
PackingGroup III
Hazardous Substances Data109-59-1(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 5111 mg/kg LD50 dermal Rabbit 1445 mg/kg
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
2-ISOPROPOXYETHANOL Usage And Synthesis
Chemical Propertiescolourless liquid
Uses2-Isopropoxyethanol was used to study the products of the gas-phase reactions of OH radical with n-butyl methyl ether and 2-isopropoxyethanol in the presence of NO. 2-Isopropoxyethanol was used to develop methodology for evaluating electromagnetic sensor performance in nonrelaxing and nonconducting (e.g., sandy soil) media
UsesEthylene glycol monoisopropyl ether (EGIE) is used as a solvent for resins, dyes, and cellulose esters, and in coatings..
UsesSolvent in latex paints, lacquers, and other coatings, resins, coalescing aids, and coupling solvents
General DescriptionA clear liquid. Density 0.903 g / cm3. Flash point 114°F. An irritant.
Air & Water ReactionsFlammable. Oxidizes in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. Water soluble .
Reactivity Profile2-ISOPROPOXYETHANOL acts both as an alcohol and ether. May react violently with strong oxidizing agents. May generate flammable and/or toxic gases with alkali metals, nitrides, and other strong reducing agents. May initiate the polymerization of isocyanates and epoxides.
HazardCombustible liquid with flash p 49C. Toxic by skin absorption.
Health HazardEGIE shows low toxicity from inhalation, ingestion, and skin absorption. The toxic symptomsaresimilartothoseproducedbythe butyl ether of the ethylene glycol. The effects noted in rats from exposure to 1000 ppm for 6 hours were hemoglobinuria, anemia, and lung congestion (Gage 1970). Other effectsobservedwereincreasesintheosmotic fragility of the red blood cells. Such effects were manifested at EGIE concentrations of >200 ppm. A 4-hour exposure to 4000 ppm was lethal to rats. In human exposure to this compound can result in anemia
LD50 value, oral (rats): 5660 mg/kg
No testicular toxicity was observed in rats from a single exposure to 3500 ppm of EGIE in air (Doe 1984)..
Health HazardMay be harmful by inhalation, ingestion or skin absorption. May cause skin and eye irritation.
Fire HazardSpecial Hazards of Combustion Products: Emits toxic fumes when heated upon decomposition.
Waste DisposalChemical incineration is the most suitable method of destruction. Drain disposal may be done for small amounts of EGIE.
2-ISOPROPOXYETHANOL Preparation Products And Raw materials
Raw materialsSodium carbonate-->2-Bromopropane-->VINYL CHLORIDE
Preparation Products2-Ethoxyethanol
1,6-ANHYDRO-3,4-O-ISOPROPYLIDENE-2-TOSYL-B-D-GALACTOPYRANOSE 1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol 5-Chloro-2-pentanone cyclic ethylene ketal Span 20 beta-D-Ribofuranose 1-acetate 2,3,5-tribenzoate Dicyclohexano-18-crown-6 Erythorbic Acid Ascorbyl Palmitate 1,2:3,5-Di-O-isopropylidene-alpha-D-xylofuranose D-(-)-Gulonic acid gamma-lactone D-RIBOFURANOSE-5-PHOSPHORIC ACID SODIUM SALT 2-ISOPROPOXYETHANOL (R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol G-STROPHANTHIN GLYCIDYL ISOPROPYL ETHER 1,2-O-ISOPROPYLIDENE-BETA-L-IDOFURANOSE D-SACCHARIC ACID 1,4-LACTONE α-Chloralose

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