1-Cyclohexenyloxytrimethylsilane

1-Cyclohexenyloxytrimethylsilane Basic information

Product Name:	1-Cyclohexenyloxytrimethylsilane
Synonyms:	(1-cyclohexen-1-yloxy)trimethyl-silan;1-(trimethylsiloxy)-cyclohexene1,1,1,3,3,3-;1-CYCLOHEXENYLOXYTRIMETHYLSILANE;(1-CYCLOHEXEN-1-YLOXY)TRIMETHYLSILANE;1-(TRIMETHYLSILOXY)CYCLOHEXENE;1-TRIMETHYLSILYLOXYCYCLOHEXENE;TRIMETHYLSILYLOXYCYCLOHEXENE;TRIMETHYLSILYLOXY-1-CYCLOHEXENE
CAS:	6651-36-1
MF:	C9H18OSi
MW:	170.32
EINECS:	229-675-1
Product Categories:	Monoalkoxysilanes;Si (Classes of Silicon Compounds);Silicon Compounds (for Synthesis);Si-O Compounds;Synthetic Organic Chemistry
Mol File:	6651-36-1.mol

1-Cyclohexenyloxytrimethylsilane Chemical Properties

Boiling point	64-65 °C15 mm Hg(lit.)
density	0.875 g/mL at 25 °C(lit.)
refractive index	n20/D 1.447(lit.)
Fp	108 °F
storage temp.	Sealed in dry,2-8°C
solubility	Not miscible or difficult to mix.
form	clear liquid
color	Colorless to Light yellow to Light orange
Specific Gravity	0.885
Sensitive	Moisture Sensitive
Hydrolytic Sensitivity	7: reacts slowly with moisture/water
BRN	1859394
Stability:	Moisture Sensitive
CAS DataBase Reference	6651-36-1(CAS DataBase Reference)
EPA Substance Registry System	Silane, (1-cyclohexen-1-yloxy)trimethyl- (6651-36-1)

Safety Information

Hazard Codes	F
Risk Statements	10
Safety Statements	16
RIDADR	UN 1993 3/PG 3
WGK Germany	3
F	10-21
Hazard Note	Flammable/Keep Cold/Moisture Sensitive
TSCA	Yes
HazardClass	3
PackingGroup	III
HS Code	2906120000

MSDS Information

1-Cyclohexenyloxytrimethylsilane Usage And Synthesis

Chemical Properties	clear yellow liquid
Uses	1-(Trimethylsiloxy)cyclohexene is used as intermediate to complex compounds, including natural products. It is also used as a pharmaceutical intermediate.
General Description	1-(Trimethylsiloxy)cyclohexene undergoes Michael addition reaction with methyl vinyl ketone in the presence of dibutyltin bis(triflate).

1-Cyclohexenyloxytrimethylsilane Preparation Products And Raw materials

Raw materials	1,2-Octanediol, 2-(trimethylsilyl)--->2-bromocyclohexanone-->Ethyl (trimethylsilyl)acetate-->1-METHOXY-1-TRIMETHYLSILYLOXYPROPENE-->TRIBUTYLSTANNYLTRIMETHYLSILANE-->DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL-->2-Chlorocyclohexanone-->Cyclohexanol,1-(1,1-dimethylethyl)-
Preparation Products	2-TERT-BUTYLCYCLOHEXANONE-->1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE--->2-(3-METHOXYPHENYL)CYCLOHEXANONE-->2,6-DIBENZYLIDENECYCLOHEXANONE-->2-BENZYLCYCLOHEXANONE-->2-BENZYLIDENECYCLOHEXANONE-->1-TRIMETHYLSILYL-2-PYRROLIDINONE-->1,1-DIMETHOXYCYCLOHEXANE-->2-PHENYLCYCLOHEXANONE-->2-Oxazolidone

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