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| | R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN Basic information |
| Product Name: | R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN | | Synonyms: | (S)-SYNPHOS(R);(S)-SYNPHOS(TM);S-(-)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN;(S)-(-)-[(5,6),(5',6')-BIS(ETHYLENEDIOXY)BIPHENYL-2,2'-DIYL](DIPHENYLPHOSPHINE);(R)-SYNPHOS(R);(R)-SYNPHOS(TM);R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN;(R)-(+)-[(5,6),(5',6')-BIS(ETHYLENEDIOXY)BIPHENYL-2,2'-DIYL](DIPHENYLPHOSPHINE) | | CAS: | 503538-68-9 | | MF: | C40H32O4P2 | | MW: | 638.63 | | EINECS: | | | Product Categories: | Chiral Phosphine;SYNPhos | | Mol File: | 503538-68-9.mol |  |
| | R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN Chemical Properties |
| Melting point | >260 °C | | Boiling point | 738.4±60.0 °C(Predicted) | | storage temp. | Inert atmosphere,Room Temperature | | form | Powder | | color | white |
| Provider | Language |
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ACROS
| English |
| | R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN Usage And Synthesis |
| Chemical Properties | White crystalline powder | | Reactions |
- A chiral diphosphine ligand used in the highly-enantioselective hydrogenation of ketoesters, hydroxyketones, ketophosphonates and succinates.
- A ligand used for the dynamic kinetic resolution of α,β−unsaturated lactones via asymmetric copper-catalyzed conjugate reduction.
- Used in the intramolecular Heck reaction for the synthesis of diterpenoids.
- Used in asymmetric Pauson-Khand reaction.
- Used in asymmetric iminonitroso Diels-Alder reaction.
- Palladium catalyzed asymmetric hydrogenation of N-tosyl ketimines
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| | R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN Preparation Products And Raw materials |
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