ChemicalBook Product Catalog Chemical Reagents Organic reagents The polycyclic compound DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Basic information
Reaction
Product Name:DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
Synonyms:(S)-(-)-2,2''-Bis-(diphenylphosphino)-1,1''-binaphthyl ruthenium dichloride;[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride;Dichloro〔(S)-(－)-2,2-bis(diphenylphosphino)-1,1-binaphthyl〕ruthenium(Ⅱ);Dichloro[(S)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),95% [(S)-BINAP]RuCl2;(S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium;-binaphthyl]dichlororuthenium;-binaphthyl]ruthenium(II),(S-BINAP)RuCl2;Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
CAS:134524-84-8
MF:C44H32Cl2P2Ru
MW:794.65
EINECS:634-379-4
Product Categories:Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Ru
Mol File:134524-84-8.mol
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Structure
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Chemical Properties
Melting point >300 ºC
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Benzene (Slightly, Heated), Dichloromethane (Slightly, Heated)
form Powder
color orange
Sensitive air sensitive
Stability:Air Sensitive, Moisture Sensitive
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39-36/37
WGK Germany 3
HS Code 28439000
MSDS Information
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Usage And Synthesis
Reaction
  1. Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
  2. Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.
Reactions of 134524-84-8
Chemical PropertiesSolid
Uses[(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium is used as a catalyst in the asymmetric synthesis of chiral δ-lactones and in the stereoselective synthesis of (hydroxy)amino acids via asymmetric hydrogenation of aminoketo esters.
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Preparation Products And Raw materials
(R)-2,2''-[5-NITROISOPHTHALAMIDOBIS(2,6-PYRIDYLENECARBAMOYLMETHOXY)]-1,1''-BINAPHTHYL (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE [(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE Dichloro[(R)-(+)-2,2’-bis(diphenylphosphino)-1,1-binaphthyl]paltinum(II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Dichloro[(S)-(-)-2,2’-bis(diphenylphosphino)-1,1-binaphthyl]paltinum(II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride [1,1'-Bis(diphenylphosphino)ferrocene]dichlorocobalt(II) (R)-DM-BINAP (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 1,1'-BINAPHTHYL DICHLORO[RAC-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II)
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