TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE

TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE Basic information
Reaction
Product Name:TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE
Synonyms:TETRAPHOS-2;TETRAPHOS-II;TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE;(Phosphinetriyl)tris(ethylene)tris(diphenylphosphine);Phosphinetriyltrisethylenetris(diphenylphosphine);Tris[2-(diphenylphosphino)ethyl]phosphine,97%;Tris(diphenylphosphinoethyl)phosphine;Tris[2-(diphenylphosphino)ethyl]phosphine, 97% 1GR
CAS:23582-03-8
MF:C42H42P4
MW:670.68
EINECS:245-754-3
Product Categories:Ligand;Achiral Phosphine;Aryl Phosphine
Mol File:23582-03-8.mol
TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE Structure
TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE Chemical Properties
Melting point 134-135 °C(lit.)
Boiling point 740.1±55.0 °C(Predicted)
form Powder
color white
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-37/39
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE Usage And Synthesis
Reaction
  1. Ligand used in the ruthenium-catalyzed hydrogenation of carbon dioxide facilitated by catalytic quantities of bicarbonate.
  2. Ligand used in the selective iron-catalyzed transfer hydrogenation of terminal alkynes.
  3. Ligand used in the selective iron-catalyzed transfer hydrogenation of nitoarenes, without base. 
Reactions of 23582-03-8
Chemical Propertieswhite to light yellow crystal powde
UsesLigand used in iron-catalyzed, greener reduction of aldehydes to alcohols under transfer hydrogenation conditions.

Fast and selective iron-catalyzed transfer hydrogenations of aldehydes
General DescriptionThis product has been enhanced for catalytic efficiency.
TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE Preparation Products And Raw materials
1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Diphenylphosphine Triethylphosphine DIETHYLPHOSPHINE TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE 1,2-BIS(PHOSPHINO)ETHANE ETHYLDIPHENYLPHOSPHINE diphenyl(2-phosphinoethyl)phosphine

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