Bis(4-tert-butylcyclohexyl) peroxydicarbonate

Bis(4-tert-butylcyclohexyl) peroxydicarbonate Basic information
Product Name:Bis(4-tert-butylcyclohexyl) peroxydicarbonate
Synonyms:Di-(4-tert.-butylcyclohexyl)-peroxydicarbonat;Bis(4-tert-butylcyclohexyl) peroxydicarbonate;Di-(4-tert-butylcyclohexyl)peroxydicarbonate;Peroyl TCP;[α,β-Peroxy]dicarbonic acid bis(4-tert-butylcyclohexyl) ester;4,4'-[Peroxybis(carbonyloxy)]bis(tert-butylcyclohexane);Bis[(4-tert-butylcyclohexyloxy)carbonyl] peroxide;Peroxybis(formic acid 4-tert-butylcyclohexyl) ester
CAS:15520-11-3
MF:C22H38O6
MW:398.53
EINECS:239-557-1
Product Categories:
Mol File:15520-11-3.mol
Bis(4-tert-butylcyclohexyl) peroxydicarbonate Structure
Bis(4-tert-butylcyclohexyl) peroxydicarbonate Chemical Properties
Melting point 91-92°C
Boiling point 435.1±28.0 °C(Predicted)
density 1.06±0.1 g/cm3(Predicted)
vapor pressure 0.01Pa at 20℃
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
color White to Off-White
Water Solubility 600ng/L at 20℃
Stability:Light Sensitive
LogP8.34
EPA Substance Registry SystemPeroxydicarbonic acid, C,C'-bis[4-(1,1-dimethylethyl)cyclohexyl] ester (15520-11-3)
Safety Information
Hazard Codes O
Risk Statements 7
Safety Statements 3-7-14-36/37/39-17
RIDADR UN 3114 5.2
WGK Germany 1
HS Code 29209090
MSDS Information
Bis(4-tert-butylcyclohexyl) peroxydicarbonate Usage And Synthesis
Chemical PropertiesBis(4-tert-butylcyclohexyl) peroxydicarbonate is crystalline solid (white powder) with slight odor, sensitive to heat and contamination, and may decompose violently or explosively at temperature 0–10°C, owing to self-accelerating exothermic decomposition due to shock, heat, or friction. To lessen the explosion risk, di-(4-tert-butylcyclohexyl) peroxydicarbonate should be stored in a temperature controlled vessel and mixed with water to form a slurry of the peroxide. Hazardous polymerization does not occur (12c). Detached storage is preferred for this chemical, including out of direct sunlight in a cool wellventilated place. It should be stored away from combustibles and other incompatible materials, including strong acids, bases, oxidizers, reducing agents, amines, and promoters/ accelerators, which may result in a violent decomposition or explosion. Refer to the Code for the Storage of Organic Peroxide Formulations (13a).
Chemical PropertiesColorless solid
UsesBis(4-(tert-butyl)cyclohexyl) Peroxydicarbonate is a useful raw material used in the preparation of polymerizable yellow azo dyes applied in artificial intraocular lens. A catalyst.
UsesDi-(4-tert-butylcyclohexyl) peroxy dicarbonate is used as polymerization initiator. No information was located for this compound.
General DescriptionCrystalline solid. Bis(4-tert-butylcyclohexyl) peroxydicarbonate is particularly heat and contamination sensitive. These materials above a given "control temperature" may decompose violently. They are often stored in a temperature controlled vessel, also mixed with water to form a slurry of the peroxide. This greatly lessens the explosion hazard risk.
Reactivity ProfileDI-(4-TERT-BUTYLCYCLOHEXYL)PEROXYDICARBONATE decomposes violently or explosively at temperatures 0-10° C. owing to self-accelerating exothermic decomposition; Several explosions were due to shock, heat or friction; amines and certain metals can cause accelerated decomposition [Bretherick, 1979 p. 156].
Bis(4-tert-butylcyclohexyl) peroxydicarbonate Preparation Products And Raw materials
Raw materials4-tert-Butylcyclohexyl chloroformate
2-Cyanoethyl N,N,N',N'-tetraisopropylphosphorodiamidite Bis(4-chlorobenzyl) azodicarboxylate tert-Butyl 2,2,2-trichloroacetimidate 4-tert-Butylcyclohexanol Benzoyl peroxide Diisopropyl peroxydicarbonate tert-Butyl acetate TERT-BUTYLCYCLOHEXANE Diethyl peroxydicarbonate tert-Butanol Bis(4-tert-butylcyclohexyl) peroxydicarbonate tert-Butyl peroxyacetate Dicumyl peroxide Di-sec-butyl peroxydicarbonate CIS-4-TERT-BUTYLCYCLOHEXANOL Di-n-butyl peroxydicarbonate(in solution,content≤27%) Di-n-propyl peroxydicarbonate Aluminum oxide

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