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Ethylmagnesium chloride

Ethylmagnesium chloride Basic information
Product Name:Ethylmagnesium chloride
Synonyms:ETHYLMAGNESIUM CHLORIDE;Ethylmagnesium Chloride (18% in Tetrahydrofuran, ca. 2mol/l);chloroethylmagnesium;ETHYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N DIETHYL ETHER;ETHYLMAGNESIUM CHLORIDE, 2.0M SOLUTION &;ETHYLMAGNESIUM CHLORIDE SOLUTION, ~2.8 M IN TETRAHYDROFURAN;ETHYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N TETRAHYDROFURAN;ETHYLMAGNESIUM CHLORIDE, 2M SOLUTION IN TETRAHYDROFURAN
CAS:2386-64-3
MF:C2H5ClMg
MW:88.82
EINECS:219-206-9
Product Categories:grignard reagent;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents;GRIGNARD REAGENTS;Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds
Mol File:2386-64-3.mol
Ethylmagnesium chloride Structure
Ethylmagnesium chloride Chemical Properties
Boiling point 66℃
density 1.00 g/mL at 20 °C
Fp 1 °F
storage temp. water-free area
form Solution
color Yellow to dark brown
Water Solubility reacts
Sensitive Air & Moisture Sensitive
BRN 3647886
InChIKeyZWNJJACKPNTXHY-UHFFFAOYSA-M
CAS DataBase Reference2386-64-3(CAS DataBase Reference)
EPA Substance Registry SystemMagnesium, chloroethyl- (2386-64-3)
Safety Information
Hazard Codes F+,C,F
Risk Statements 12-14-20/21/22-34-40-14/15-11-22-19-67-37
Safety Statements 26-30-36/37/39-43-45-7/8-33-16-6A-43A-24/25
RIDADR UN 3399 4.3/PG 1
WGK Germany 1
F 1-3-10
TSCA Yes
HazardClass 4.3
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
Ethylmagnesium chloride Usage And Synthesis
Chemical PropertiesDARK BROWN SOLUTION
UsesGrignard-type reactions.
UsesEthylmagnesium chloride solution can be used:
  • In Cp2ZrCl2 catalyzed ethylcarboxylation of alkenes using carbon dioxide to corresponding carboxylic acids.
  • In the preparation of cyclobutylmagnesium carbenoids by reacting with 1-chlorocyclobutyl p-tolyl sulfoxides.

DefinitionCHEBI:Ethylmagnesium chloride is an alkylmagnesium halide. It has a role as a Grignard reagent.
HazardFlammable, dangerous fire risk.
Ethylmagnesium chloride Preparation Products And Raw materials
Preparation ProductsTetrahydrolinalool-->Isotretinoin-->Delta Damascone-->TETRAETHYLLEAD-->4-(1-Hydroxy-1-methylpropyl)-2-propyl-1H-Imidazole-5-carboxylic acidethylester-->Ethyldichlorosilane-->ETHYL-O-TOLYL KETONE-->1-PHENYL-1-CYCLOPROPANOL-->2-Ethylpyridine-->Methyl(triphenyl)phosphonium chloride-->2-Ethyl-1-decanol-->1-(4-Bromo-2-chlorophenyl)propan-1-one-->1-(4-bromo-3-fluorophenyl)propan-1-one
Butylmagnesium chloride OCTYLMAGNESIUM CHLORIDE ISOBUTYLMAGNESIUM CHLORIDE CYCLOPENTYLMAGNESIUM CHLORIDE Zinc chloride PHENYLMAGNESIUM CHLORIDE TERT-BUTYLMAGNESIUM CHLORIDE Vinylmagnesium chloride Benzylmagnesium chloride Ethylmagnesium chloride PROPYLMAGNESIUM CHLORIDE ISOPROPYLMAGNESIUM CHLORIDE Choline chloride Allylmagnesium chloride Diethyl chlorothiophosphate Potassium chloride SEC-BUTYLMAGNESIUM CHLORIDE 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile
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